Magnetic properties of Co-2(OH)(AsO4)

被引:13
|
作者
Rojo, JM [1 ]
Mesa, JL [1 ]
Lezama, L [1 ]
Barberis, GE [1 ]
Rojo, T [1 ]
机构
[1] UNIV BASQUE COUNTRY, FAC CIENCIAS, DEPT QUIM INORGAN, E-48080 BILBAO, SPAIN
关键词
Co-2(OH)(AsO4); hydrothermal synthesis; EPR; magnetic properties;
D O I
10.1016/0304-8853(95)01176-5
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Samples of dicobalt hydroxide arsenate, Co-2(OH)(AsO4), and magnesium derivatives were prepared under hydrothermal conditions. An EPR study shows that there exists a strong preference of the Co2+ ions for the octahedral sites in the crystal structure, as well as a large magnetic anisotropy, parametrized by its spin Hamiltonian parameters g and A. The results of magnetic susceptibility measurements are consistent with 3D antiferromagnetic behaviour.
引用
收藏
页码:493 / 495
页数:3
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