Synthesis and Crystal Structure of [Y(C6H4NO2)2(H2O)4]n•nCl

被引：2
|
作者：
Chen, Wen-Tong [1 ]
Luo, Zhi-Gang [1 ]
机构：
[1] Jinggangshan Univ, Inst Appl Chem, Sch Chem & Chem Engn, Jiangxi Prov Key Lab Coordinat Chem, Jian 343009, Jiangxi, Peoples R China
来源：
ASIAN JOURNAL OF CHEMISTRY | 2013年 / 25卷 / 07期
关键词：
Crystal; Hydrothermal; Yttirium; Isonicotinic; Supramolecule; COMPLEXES; SILICA; PROBE;
D O I：
10.14233/ajchem.2013.14124
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel yttirium complex with the general formula [Y(C6H4NO2)(2)(H2O)(4)](n)center dot nCl (1) has been prepared via a hydrothermal synthesis method and structurally characterized by X-ray diffractions. Complex 1 crystallizes in the space group Pbcn of the orthorhombic system with four formula units in a cell: a = 8.9401(14), b = 19.576(3), c = 10.0063(13) angstrom, V = 1751.2(4) angstrom(3), C12H16N2O8ClY, M-r = 440.63, D-c = 1.671 g/cm(3), T = 293.15 K, F(000) = 888 and R1/wR(2) = 0.0421/0.0991 for 1256 observed reflections [I > 2 sigma(I)] and 1539 unique reflections. Complex 1 features a novel one-dimensional (1-D) chain-like structure.
引用
收藏
页码：4077 / 4079
页数：3
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