Three new three dimensional Zn(II)-benzenetetracarboxylate coordination polymers: Syntheses, crystal structures and luminescent properties

被引：13
|
作者：
Luo, Yu-Hui [1 ]
Tao, Chuan-Zhou [1 ]
Zhang, Dong-En [1 ]
Ma, Juan-Juan [1 ]
Liu, Lin [1 ]
Tong, Zhi-Wei [1 ]
Yu, Xiao-Yang [2 ]
机构：
[1] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222000, Jiangsu, Peoples R China
[2] Jilin Inst Chem Technol, Jilin 132022, Jilin, Peoples R China
来源：
POLYHEDRON | 2017年 / 123卷
基金：
中国国家自然科学基金;
关键词：
1,2,4,5-Benzenetetracarboxylic acid; Zinc(II) compounds; Coordination polymers; Hydrothermal reaction; Luminescent property; COMPLEXES;
D O I：
10.1016/j.poly.2016.10.045
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Three novel coordination polymers, namely, [Zn-2(betc)(L-1)H(H2O)].2H(2)O (1), [Zn-2(btec)(L-2)(2)] (2) and [Zn-5(btec)(2)(L-3)(1.5)(OH)(2)]-2H(2)O (3) (L-1 = 3,5-di(1H-imidazol-1-yl)benzoate, L-2 = 1,3-bis((1H-1,2,4-triazol-1-yl)methyl)benzene and L-3 = 1,3-di(1H-1,2,4-triazol-1-yl)propane), have been hydrothernIally synthesized. Compound 1 shows a three dimensional (3D) framework with fsc-3,5-P4/mbm topology. Compound 2 reveals a 3D pillar-layered framework with the presence of 3-fold left- and right-handed helical chains. Compound 3 also exhibits a 3D framework based on 1D zinc chains. In addition, the luminescent properties for 1-3 have also been investigated. (C) 2016 Elsevier Ltd. All rights reserved.
引用
收藏
页码：69 / 74
页数：6
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