Syntheses, crystal structures and properties of three novel coordination polymers with tripodal imidazole-containing ligands and benzenetetracarboxylate

被引：0
|
作者：
Zhi Su
Jian Fan
WeiYin Sun
机构：
[1] Nanjing University,State Key Laboratory of Coordination Chemistry; Nanjing National Laboratory of Microstructures; Coordination Chemistry Institute, School of Chemistry and Chemical Engineering
来源：
Science China Chemistry | 2010年 / 53卷
关键词：
coordination polymer; self-penetration; crystal structure; thermal stability; photoluminescence property;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Three novel coordination polymers, [Ni2(tib)2(btec)]·2H2O (1), [Co2(tib)2(btec)]·2H2O (2) and [Zn4(tib)2(btec)Cl4]·2H2O (3), have been synthesized by using mixed ligands of 1,3,5-tris(1-imidazolyl)benzene (tib) and 1,2,4,5-benzenetetracarboxylic acid (H4btec) under hydrothermal conditions. Complexes 1 and 2 have the same structure and are rare three-dimensional (3D) self-penetrating (3,4,5)-connected nets, while complex 3 is an unprecedented (3,4)-connected 3D net. The different structures of 1 (2) and 3 are ascribed to the distinct coordination geometry of the metal centers. The thermal stability and photoluminescence property of the complexes were investigated.
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页码：2164 / 2169
页数：5
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