alpha-Allylation of carbonyl compounds via silyl enol ethers and silyl ketene acetals using a hypervalent iodine reagent

被引：4
|
作者：
Moriarty, RM
Epa, WR
Prakash, O
机构：
[1] Chemistry Department, University of Illinois at Chicago, Chicago, IL 60607
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 1997年 / 07期
关键词：
D O I：
10.1039/a701224a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Oxidation of allyltrimethylsilane with iodosobenzene and trimethylsilyl trifluoromethanesulfonate followed by treatment with trimethylsilyl enol ethers of ketones or trimethylsilyl ketene acetals of esters/lactones provides a new method for the alpha-allylation of the corresponding carbonyl compounds.
引用
收藏
页码：262 / 263
页数：3
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