Novel Receptor for the Rapid Reaction and Colorimetric Detection of HSO3- in Aqueous Solutions

被引：4
|
作者：
Yang Wen-long
Li Qiao
Wei Tai-bao [1 ]
Zhang You-ming
Lin Qi
Shi Bing-bing
Zhang Peng
机构：
[1] Northwest Normal Univ, Minist Educ China, Key Lab Ecoenvironm Related Polymer Mat, Lanzhou 730070, Peoples R China
来源：
CHEMICAL RESEARCH IN CHINESE UNIVERSITIES | 2013年 / 29卷 / 02期
基金：
中国国家自然科学基金;
关键词：
Bisulfite anion sensor; 2-Aminobenzimidazole; Aqueous solution; Single recognition; Colorimetry; RECOGNITION PROPERTIES; SELECTIVE DETECTION; FLUORESCENT-PROBE; ANION; FLUORIDE; DESIGN; SENSOR;
D O I：
10.1007/s40242-013-2395-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel high-yield Schiff base was designed and synthesized as an anion receptor that specifically select HSO3- anions in aqueous solutions of H2O/DMSO(15:85, volume ratio), which can be detected via colorimetry under direct visualization. The sensor exhibited different results for other anions, such as F-, Cl-, Br-, I-, H2PO4-, AcO-, HSO4- and ClO4-. The changes in the UV-Vis spectra also show the specific recognition of HSO3-, rather than similar anions H2PO4- and HSO4- in the same aqueous solution. The detection limit of HSO3- was 1 x 10(-6) mol/L.
引用
收藏
页码：236 / 238
页数：3
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