Stabilization of discrete [Cu(C2O4)2(H2O)2]2- dianions in the solid state by an extensive hydrogen bonded network

被引：10
|
作者：
Keene, TD [1 ]
Hursthouse, MB [1 ]
Price, DJ [1 ]
机构：
[1] Univ Southampton, Sch Chem, Southampton SO17 1BJ, Hants, England
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2004年 / 630卷 / 03期
关键词：
copper; oxalate complexes; bifurcated hydrogen bonds; crystal structure;
D O I：
10.1002/zaac.200300373
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dominant species in aqueous copper(II) solutions containing a high concentration of oxalate (ox) is trans[Cu(ox)(2)(H2O)(2) ](2-), yet the ability of the oxalate anion to bridge metal ions means that very few examples of this isolated anion are seen in solid state structures. The structure of [pipH(2)](2+)[Cu(ox)(2)(H2O)(2)](2-). 2H(2)O (pip = piperazine) (1) comprises discrete ions held in a complex 3-dimensional hydrogen bonded network.
引用
收藏
页码：350 / 352
页数：3
相关论文
共 50 条
  • [1] Speciation and transformation in the synthesis of Cu4(im)4(C4O3H6)2(NO2)4(H2O)4 and [(phen)Cu(C2O4)(H2O)]•H2O
    Gong, Yun
    Li, Hui
    Li, Yang Guang
    Wang, Yong Hui
    Tang, Wang
    Hu, Chang Wen
    JOURNAL OF COORDINATION CHEMISTRY, 2007, 60 (01) : 61 - 71
  • [2] BARIUM COPPER(II) OXOCARBON COMPOUNDS - SYNTHESIS, CRYSTAL-STRUCTURES AND THERMAL BEHAVIORS OF [BA(H2O)(5)][CU(C2O4)(2)(H2O)] AND [BA(C4O4)(0.5)(H2O)(2)](2)[CU(C4O4)(2)(H2O)(2)]
    BOUAYAD, A
    TROMBE, JC
    GLEIZES, A
    INORGANICA CHIMICA ACTA, 1995, 230 (1-2) : 1 - 7
  • [3] The thermal dehydration and decomposition of Ba[Cu(C2O4)2(H2O)]·5H2O
    J. Bacsa
    D. J. Eve
    M. E. Brown
    Journal of thermal analysis, 1997, 50 : 33 - 50
  • [4] The thermal dehydration and decomposition of Ba[Cu(C2O4)(2)(H2O)].5H(2)O
    Bacsa, J
    Eve, DJ
    Brown, ME
    JOURNAL OF THERMAL ANALYSIS, 1997, 50 (1-2): : 33 - 50
  • [5] PHOTOCHEMICAL DECOMPOSITION OF K2[CU(C2O4)2].2H2O IN THE SOLID-STATE
    TANAKA, K
    JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1981, 43 (11): : 2999 - 3001
  • [6] Crystal-to-Crystal Transformation from K2[Co(C2O4)2(H2O)2]•4H2O to K2[Co(μ-C2O4)(C2O4)]
    Zhang, Bin
    Zhang, Yan
    Chang, Guangcai
    Wang, Zheming
    Zhu, Daoben
    MAGNETOCHEMISTRY, 2021, 7 (06)
  • [7] MAGNETIC SUSCEPTIBILITY OF SOLID SOLUTIONS U(C2O4)2 . 2H2/ - TH(C2O4) . 2H2O
    AMINOV, TG
    EVDOKIMO.VB
    ZELENTSO.VV
    DOKLADY AKADEMII NAUK SSSR, 1966, 170 (03): : 615 - &
  • [8] Hydrothermal synthesis and crystal structures of new uranyl oxalate hydroxides:: α- and β-[(UO2)2(C2O4)(OH)2(H2O)2] and [(UO2)2(C2O4)(OH)2(H2O)2] • H2O
    Duvieubourg, L
    Nowogrocki, G
    Abraham, F
    Grandjean, S
    JOURNAL OF SOLID STATE CHEMISTRY, 2005, 178 (11) : 3437 - 3444
  • [9] K2[Mo2O4(C2O4)2(H2O)2]•3H2O
    Strukan, N
    Cindric, M
    Kamenar, B
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : 639 - 641
  • [10] Reversible Photochromic Properties of Ti2O3(H2O)2(C2O4) . H2O Material
    Hu, Kangkai
    Lei, E.
    Zhao, Dan
    Guo, Zhengang
    Zhang, Bo
    CHEMNANOMAT, 2022, 8 (01)
12345