Substituted Acene Derivatives: Synthesis, Optical Property and Self-assembly Behavior

被引：4
|
作者：
Liang, Zhihua [1 ]
Zhai, Guixia [2 ]
Fan, Yanwei [2 ]
Wang, Shifa [1 ]
Xiao, Jinchong [2 ]
机构：
[1] Nanjing Forestry Univ, Coll Chem Engn, Nanjing 210037, Jiangsu, Peoples R China
[2] Hebei Univ, Key Lab Chem Biol Hebei Prov, Coll Chem & Environm Sci, Baoding 071002, Peoples R China
来源：
CHEMISTRYSELECT | 2018年 / 3卷 / 09期
基金：
中国国家自然科学基金;
关键词：
acene; optical property; self-assembly; single crystal; substituent; LIGHT-EMITTING-DIODES; CONJUGATED POLYMER NANOPARTICLES; PHYSICAL-PROPERTIES; TWISTED ACENES; SOLAR-CELLS; TWISTACENE; HETEROTWISTACENES; CRYSTAL;
D O I：
10.1002/slct.201702897
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel twistacene 11,12-dichloro-9,14-diphenyldibenzo [de,qr]tetracene (TPyC) has been synthesized in one pot through classical Diels-Alder cycloaddition reaction and fully characterized. Its analogues TPyO, TPyS, TPyF and TPyB were re-prepared through the reported methods. All of them emitted blue fluorescence in toluene solution. The self-assembly properties based on the as-prepared molecules were examined in detail by re-precipitation method, suggesting that the terminal substituents, temperature and solvent could affect the aggregation morphology in large part.
引用
收藏
页码：2692 / 2696
页数：5
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