Hydrothermal Synthesis, Crystal Structure, and Luminescence Property of Two Lanthanide Coordination Polymers with Diglycolic Acid

被引：2
|
作者：
Li, Xia [1 ]
Ju, Yan-Ling [1 ]
机构：
[1] Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China
来源：
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2009年 / 39卷 / 03期
关键词：
Lanthanide coordination polymers; Diglycolic acid; Hydrothermal synthesis; Crystal structure; Luminescence property; RARE-EARTH CARBOXYLATES; ORGANIC FRAMEWORKS;
D O I：
10.1007/s10870-008-9462-3
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
Two new coordination polymers {[Tb-2(C4H4O5)(3)center dot 4H(2)O]center dot 2H(2)O}(n) (1) and {[La-2(C4H4O5)(3)center dot 3H(2)O]center dot 3H(2)O}(n) (2) (C4H4O52- = diglycolato) were prepared by hydrothermal reaction and characterized by X-ray crystallography. The two complexes have different network structures through carboxylate oxygen atoms and ether oxygen atoms from diglycolato ligands linking lanthanide ions. The characteristic transition bands 5D4 -> 7FJ (J = 6 - 3) of Tb(III) ion are observed in complex 1.
引用
收藏
页码：213 / 220
页数：8
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