A novel 3-D metal-organic framework constructed from a negative 2-D layer [Cu2(BTB)2]2- and long linkers [Cu(4,4′-bipy)2]2+:: Synthesis, crystal structure and blue fluorescence

被引：38

作者：

Liu, B ^{[1
]}

Xu, L

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

[2] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 04期

关键词：

copper(II); 1,2,3-benzenetricarboxylic acid; diffusion; structure; fluorescence;

D O I：

10.1016/j.inoche.2006.01.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 3-D novel coordination polymer {[Cu-5(BTB)(4)(4,4'-bipy)(2)(H2O)(6)][Cu(4,4'-bipy)(H2O)(4)]}(n) . 8nH(2)O (H3BTB = 1,2,3-benzene-tricarboxylic acid), containing 1-D chains [Cu(4,4'-bipy)(H2O)(4)](n), is obtained from the diffusion method. A negative 2-D layered structure [Cu-2(BTB)(2)](2-) along the bc-plane based on tetranuclear paddle-wheel clusters has been generated from 1-D chains along the b - c vector linked by BTB3-. A 3-D metal-organic framework is further constructed from the negative 2-D layer [Cu-2(BTB)(2)](2-) and long linker [Cu(4,4'-bipy)(2)](2+). The compound produces blue fluorescence with emission at 417 nm possibly assigned to LMCT. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：364 / 366

页数：3

共 50 条

[41] Synthesis, crystal and molecular structure of complex [Cu2(Gly-GlyO)2(4,4′-bpy)(OH)2].10H2O
Guo, XY
Zhang, WX
Cui, AL
Shen, LC
Wang, FS
Li, ZY
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1998, 19 (04): : 629 - 632
[42] A 2D polymer constructed through bridging oxalato and 4,4′-bipyridine ligands:: crystal structure and magnetic behavior of [Cu3(μ-ox)3(μ-4,4′-bpy)2(4,4′-bpy)2]n
Castillo, O
Alonso, J
García-Couceiro, U
Luque, A
Román, P
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (07) : 803 - 806
[43] Intramolecular versus intermolecular exchange pathways in the binuclear complex [Cu2(H2tea)2(4,4'-bipy)](ClO4)2•3H2O (H3tea=triethanolamine and 4,4'-bipy=4,4'-bipyridine)
Tudor, V
Kravtsov, V
Julve, M
Lloret, F
Simonov, YA
Lipkowski, J
Buculei, V
Andruh, M
POLYHEDRON, 2001, 20 (26-27) : 3033 - 3037
[44] Structural, thermal, and magnetic properties of three transition metal-4,4′-bipyridine coordination polymers:: [Ni(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Co(4,4′-bipy)3(H2O)2](ClO4)2•1.4(4,4′-bipy)•3(H2O); [Cu(4,4′-bipy)3(DMSO)2](ClO4)2•2(4,4′-bipy)
Woodward, JD
Backov, R
Abboud, KA
Ohnuki, H
Meisel, MW
Talham, DR
POLYHEDRON, 2003, 22 (20) : 2821 - 2830
[45] Hydrothermal Synthesis and Crystal Structure of One Novel 1-D Copper(Ⅱ)-organic Framework:{[Cu2(PP)2(CBPC)]2·7H2O}n
魏培海
吴小园
范黎明
李大成
张修堂
窦建民
刘新征
石聪文
结构化学, 2010, 29 (12) : 1774 - 1779
[46] Synthesis and crystal structure of [N(Hex)4]∞3[Cu2(CN)3]
Pretsch, T
Brüdgam, I
Hartl, H
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2003, 629 (06): : 942 - 944
[47] Synthesis, Crystal Structure and Thermal Stability Properties of a Binuclear Copper(II) Coordination Polymer {[Cu2(4,4′-bipy)2(o-ABA)4(H2O)2][(H2O)2]}n
Liu Ting
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2010, 29 (02) : 195 - 198
[48] Solution synthesis and crystal structure of a 2D coordination polymeric complex [Cu(μ-I)(μ-4,4-bipy)]n
Song Yan-Wei
Liu Yu-Jie
Zhang Qian-Feng
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2006, 22 (07) : 1227 - 1230
[49] A Novel 3D Supramolecular Network Constructed from [Cu（4,4'-bipyridine）(O2CMe)2]2 Molecular Ladders by Hydrogen Bonding
YANG Ea② WANG Xiao-Qinb QIN Ye-Yanb a (College of Chemistry & Materials Science
结构化学, 2006, (11) : 1365 - 1368
[50] Synthesis and Crystal Structure of 2D Coordination Polymer {[Cu(dps)2(DMSO)2](ClO4)2}n Based on 4,4′-Dipyridyl Sulfide
A. N. Morozov
L. D. Popov
V. V. Tkachev
E. A. Raspopova
V. A. Chetverikova
S. N. Lyubchenko
G. V. Shilov
Russian Journal of General Chemistry, 2019, 89 : 82 - 86

← 1 2 3 4 5 →