C-H functionalization of tetramethylsilane employing a borylnitrene

被引：14

作者：

Mueller, Matthias ^{[1
]}

Maichle-Moessmer, Caecilia ^{[2
]}

Bettinger, Holger F. ^{[1
]}

机构：

[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany

[2] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 100期

关键词：

CARBON-HYDROGEN-BONDS; INTERMOLECULAR ACTIVATION; METHANE; COMPLEXES; INSERTION; INSIGHTS;

D O I：

10.1039/c3cc47753c

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN(3), pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photo-product, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a bisborylated aminoborane.

引用

页码：11773 / 11775

页数：3

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