C-H functionalization of tetramethylsilane employing a borylnitrene

被引：14
|
作者：
Mueller, Matthias [1 ]
Maichle-Moessmer, Caecilia [2 ]
Bettinger, Holger F. [1 ]
机构：
[1] Univ Tubingen, Inst Organ Chem, D-72076 Tubingen, Germany
[2] Univ Tubingen, Inst Anorgan Chem, D-72076 Tubingen, Germany
来源：
CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 100期
关键词：
CARBON-HYDROGEN-BONDS; INTERMOLECULAR ACTIVATION; METHANE; COMPLEXES; INSERTION; INSIGHTS;
D O I：
10.1039/c3cc47753c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The irradiation of 2-azido-4,4,5,5-tetramethyl-1,3,2-dioxaborol (pinBN(3), pin = pinacolato) generates the corresponding borylnitrene that easily inserts into the CH bond of tetramethylsilane. This primary photo-product, a monoborylated aminoborane, undergoes a subsequent reaction with pinBN3 forming a bisborylated aminoborane.
引用
收藏
页码：11773 / 11775
页数：3
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