Ionic Liquids and the Heck Coupling Reaction: An Update

被引：25
|
作者：
Prediger, Patricia [1 ,2 ]
Genisson, Yves [1 ]
Duarte Correia, Carlos Roque [2 ]
机构：
[1] Univ Toulouse 3, CNRS, UMR5068, F-31062 Toulouse, France
[2] Univ Estadual Campinas, UNICAMP, Inst Quim, BR-13084971 Sao Paulo, Brazil
来源：
CURRENT ORGANIC CHEMISTRY | 2013年 / 17卷 / 03期
基金：
巴西圣保罗研究基金会;
关键词：
Ionic liquids; Heck reaction; Palladium-nanoparticles; N-heterocyclic carbenes; CATALYZED MIZOROKI-HECK; ARENEDIAZONIUM SALTS; RECYCLABLE CATALYST; HIGHLY EFFICIENT; PD NANOPARTICLES; SUZUKI; ARYLATION; COMPLEX; LIGAND; DERIVATIVES;
D O I：
10.2174/1385272811317030006
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this review update we provide a critical analysis of recent results concerning the use of ionic liquids (ILs) as viable, effective, and environmental friendly media for the Heck reactions (HR). The examples selected illustrate the multifaceted action of ILs as nanoparticles stabilizers, promoters of ligand-assisted HR, promoters of phosphine-free HR, solvent for the Heck-Matsuda reactions employing arenediazonium salts, in the dehydrative Heck olefination, and as charged-tagged pre-catalysts. These selected reports aim at demonstrating the scope and the impact of Ils on new discoveries, as well as to illustrate the new opportunities and challenges they offer for those interested in catalysis and organic synthesis in general.
引用
收藏
页码：238 / 256
页数：19
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