N5+:: A novel homoleptic polynitrogen ion as a high energy density material

被引：0
|
作者：
Christe, KO [1 ]
Wilson, WW
Sheehy, JA
Boatz, JA
机构：
[1] USAF, Res Lab, Propuls Sci & Adv Concepts Div, Edwards AFB, CA 93524 USA
[2] Univ So Calif, Loker Hydrocarbon Res Inst, Los Angeles, CA 90089 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1999年 / 38卷 / 13-14期
关键词：
density functional calculations; isotopic labeling; nitrogen; NMR spectroscopy; vibrational spectroscopy;
D O I：
10.1002/(SICI)1521-3773(19990712)38:13/14<2004::AID-ANIE2004>3.0.CO;2-7
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Only the third known example of a homoleptic polynitrogen species besides N2 and N3-, the N5+ ion possesses surprising stability and can be isolated on a macroscopic scale as its AsF6- salt. The assignment of the C(2v)-symmetric structure (shown schematically) predicted by calculations was supported by IR and Raman as well as 14N and 15N NMR spectroscopic studies of the isotopically labeled product.
引用
收藏
页码：2004 / 2009
页数：6
相关论文
共 50 条
  • [21] A novel Ni3N/graphene nanocomposite as supercapacitor electrode material with high capacitance and energy density
    Yu, Yu
    Gao, Wenyu
    Shen, Zongxu
    Zheng, Qing
    Wu, Hao
    Wang, Xi
    Song, Weiguo
    Ding, Kejian
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (32) : 16633 - 16641
  • [22] High Power Guiding and Electron Acceleration in Pure N5+ Plasma Channels
    Goers, A. J.
    Yoon, S. J.
    Hine, G. A.
    Elle, J. A.
    Milchberg, H. M.
    2014 CONFERENCE ON LASERS AND ELECTRO-OPTICS (CLEO), 2014,
  • [23] Ambient-Pressure Recoverable Polynitrogen Solids Assembled by Pentazolate Rings with High Energy Density
    Lin, Shuyi
    Xu, Meiling
    Liang, Yiwei
    Yuan, Xuanhao
    Zhang, Yiming
    Wang, Feilong
    Hao, Jian
    Li, Yinwei
    Inorganic Chemistry, 2022, 61 (39) : 15532 - 15539
  • [24] Low Energy N5+ Ion Induced Modification on the Flower-Like ZnSe Nanostructured Thin Films: Structural and Optical Properties
    Bakiyaraj, G.
    Krishna, J. B. M.
    Taki, G. S.
    Dhanasekaran, R.
    ASIAN JOURNAL OF CHEMISTRY, 2013, 25 : S211 - S213
  • [25] All-nitrogen ion-based compounds as energetic oxidizers: a theoretical study on [N5+][NO3-], [N5+][N(NO2)2-], [NO2+][N5-] and NO2-N3
    Sun, Qi
    Wang, Pengcheng
    Lin, Qiuhan
    Lu, Ming
    NEW JOURNAL OF CHEMISTRY, 2020, 44 (26) : 11188 - 11195
  • [26] Ambient-Pressure Recoverable Polynitrogen Solids Assembled by Pentazolate Rings with High Energy Density
    Lin, Shuyi
    Xu, Meiling
    Liang, Yiwei
    Yuan, Xuanhao
    Zhang, Yiming
    Wang, Feilong
    Hao, Jian
    Li, Yinwei
    INORGANIC CHEMISTRY, 2022, : 15532 - 15539
  • [27] The ionic salts with super oxidizing ions O2+ and N5+: Potential candidates for high-energy oxidants
    Yang, Xinbo
    Li, Nan
    Li, Yuchuan
    Pang, Siping
    FRONTIERS IN CHEMISTRY, 2022, 10
  • [28] A novel all-nitrogen molecular crystal N16 as a promising high-energy-density material
    Zhao, Lei
    Liu, Shijie
    Chen, Yuanzheng
    Yi, Wencai
    Khodagholian, Darlar
    Gu, Fenglong
    Kelson, Eric
    Zheng, Yonghao
    Liu, Bingbing
    Miao, Mao-sheng
    DALTON TRANSACTIONS, 2022, 51 (24) : 9369 - 9376
  • [29] Nanoporous Cathode Material for High-Energy-Density Sodium-Ion Batteries
    Ding, Haiyang
    Li, Hao
    Tao, Qingdong
    Ren, Jianhui
    He, Jiafeng
    ACS APPLIED NANO MATERIALS, 2023, 7 (01) : 243 - 252
  • [30] Ti(N5)4 as a Potential Nitrogen-Rich Stable High-Energy. Density Material
    Choi, Changhyeok
    Yoo, Hae-Wook
    Goh, Eun Mee
    Cho, Soo Gyeong
    Jung, Yousung
    JOURNAL OF PHYSICAL CHEMISTRY A, 2016, 120 (24): : 4249 - 4255
12345