Magnetostructural transformation and its multiple functional properties for Co-doped Ni56Mn18Ga26 Heusler alloy

The crystal structures, martensitic transformations (MT) and magnetic properties of polycrystalline Ni56- xCoxMn18Ga26 (x = 0, 1, 2) alloys have been investigated comprehensively. These alloys exhibit an un-modulated martensitic structure (L1(0)) at room temperature. In the Co free alloy, a magneto-structural coupling MT is presented. With increasing Co content, however, the MT moves to a higher temperature and finally partly splits off from ferromagnetic transition at x = 2. Simultaneously, two successive magneto-structural transformations were observed at x = 1, which could be ascribed to the existence of an intermartensitic transition (7 M <-> L1(0)). Owing to the evolution of MT with Co doping, the magnetization of paramagnetic (PM) austenite is increased slightly, while the ferromagnetic (FM) martensite is almost unchanged. The multiple functional properties associated with the field-induced MT were also investigated in these alloys. It was found that the optimized magnetostrain amounts to similar to 0.12% in the alloy with x = 2. In addition, the refrigerant capacity (RC) with the values of 50 J/kg and 49 J/kg were obtained in the alloy with x = 0 and x = 1, respectively. (C) 2016 Elsevier B.V. All rights reserved.