Preparation and Application of a New Supported Nicotine-Based Organocatalyst for Synthesis of Various 1,5-Benzodiazepines

被引：17

作者：

Korbekandi, Mehri Moeini ^{[1
]}

Nasr-Esfahani, Mahboobeh ^{[1
]}

Mohammadpoor-Baltork, Iraj ^{[1
]}

Moghadam, Majid ^{[1
]}

Tangestaninejad, Shahram ^{[1
]}

Mirkhani, Valiollah ^{[1
]}

机构：

[1] Univ Isfahan, Catalysis Div, Dept Chem, Esfahan 8174673441, Iran

来源：

CATALYSIS LETTERS | 2019年 / 149卷 / 04期

基金：

美国国家科学基金会;

关键词：

Organocatalyst; Nicotine; 1; 5-Benzodiazepines; Bis-1; 5-benzodiazepines; Water media; NANOSILICA TRIAZINE DENDRIMER; ONE-POT SYNTHESIS; IONIC LIQUIDS; MULTICOMPONENT SYNTHESIS; REUSABLE CATALYST; HIGHLY EFFICIENT; SILICA; NANOPARTICLES; DERIVATIVES; AGENTS;

D O I：

10.1007/s10562-019-02668-z

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A new nicotine-based organocatalyst supported on silica nanoparticles (Fe(III)-NicTC@nSiO(2)) was prepared and characterized by different techniques. A series of 1,5-benzodiazepines derivatives were smoothly synthesized via the tandem process, starting from o-phenylenediamine and dimedone (or 1,3-cyclohexanedione), followed by addition of aldehyde in the presence Fe(III)-NicTC@nSiO(2) catalyst in water at room temperature. The Fe(III)-NicTC@nSiO(2) was also applied as an efficient catalyst for the selective synthesis of mono- and bis-1,5-benzodiazepines. Excellent yields and selectivity, short reaction time, mild conditions, and reusability of the catalyst are valuable features of this method.

引用

页码：1057 / 1066

页数：10

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