Dielectric relaxation study of glycine-water mixtures using time domain reflectometry technique

被引:6
|
作者
Talware, R. B. [1 ]
Hudge, P. G. [1 ]
Joshi, Y. S. [1 ]
Kumbharkhane, A. C. [1 ]
机构
[1] Swami Ramanand Teerth Marathwada Univ, Sch Phys Sci, Nanded 431606, India
关键词
dielectric study; glycine; TDR technique; POLAR LIQUIDS; POLARIZATION; BEHAVIOR;
D O I
10.1080/00319104.2010.551345
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The complex permittivity of glycine in water mixture for various temperatures and concentrations have been measured as a function of frequency between 10MHz and 30GHz using time domain reflectometry technique. Dielectric parameters, i.e. static dielectric constant and relaxation time were obtained from the complex permittivity spectra using nonlinear least square fit method. The dielectric relaxation parameter increases with an increase in molar concentration of glycine due to the formation of hydrogen bond groups by glycine molecule in an aqueous solution medium. The activation entropy, activation enthalpy and Kirkwood correlation factor have also been determined for glycine-water mixtures.
引用
收藏
页码:102 / 112
页数:11
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