Studies on the reaction mechanism of CH4/CO2 reforming over Co/gamma-Al2O3 catalyst

被引：11
|
作者：
Lu, Y [1 ]
Yu, CC [1 ]
Xue, JZ [1 ]
Liu, Y [1 ]
Shen, SK [1 ]
机构：
[1] CHINESE ACAD SCI, LANZHOU INST CHEM PHYS, STATE KEY LAB OXO SYNTHESIS & SELECT OXIDAT, LANZHOU 730000, PEOPLES R CHINA
来源：
CHEMISTRY LETTERS | 1997年 / 06期
关键词：
D O I：
10.1246/cl.1997.515
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
XPS/AES and pulse reaction characterizations were combined to study the reaction mechanism of CH4/CO2 reforming to syngas over Co/gamma-Al2O3. Surface carbide carbons formed from CH4 dissociation were active C species for CO generation. Metallic Co species played an important role in dissociating CH4 to form carbide carbon and H-2, abstracting an O atom from CO2 molecule, and transferring O atom to carbide to form CO.
引用
收藏
页码：515 / 516
页数：2
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