A porous Cu(II) metal-organic framework: Synthesis, crystal structure and gas adsorption properties

被引：10

作者：

Li, Wu-Wu ^{[1
]}

Guo, Ying ^{[1
]}

Zhang, Wei-Hong ^{[1
]}

机构：

[1] Xianyang Normal Univ, Coll Chem & Chem Engn, Xianyang 712000, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2017年 / 1143卷

关键词：

Solvothermal reactions; Cu(II) compound; Gas adsorption; Light hydrocarbons; HIGHLY SELECTIVE SORPTION; LIGAND; CAPACITY; CO2; HYDROCARBONS; ACETYLENE; UNITS;

D O I：

10.1016/j.molstruc.2017.04.068

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Presented here is a new porous Cu(II) metal-organic framework, namely [Cu(tdc)(H2O)](n)center dot n(DMA) (1 H(2)tdc = thiophene-2,5-dicarboxylic acid, DMA = N,N'-dimethylacetamide), which was obtained by the self-assembly reaction of CuCl2 and H(2)tdc under solvothermal conditions. Single crystal X-ray diffraction analysis revealed that compound 1 features a 3D porous framework based on ID chain structure sub-units, and the 1D rhombohedral channels are occupied by the lattice DMA molecules. Gas adsorption studies reveal that this desolvated sample exhibit high uptake capacity for light hydrocarbons. (C) 2017 Elsevier B.V. All rights reserved.

引用

页码：20 / 22

页数：3

共 50 条

[1] A Cu(II) metal-organic framework based on an angular ligand with a bulky uncoordinated group: synthesis, structure, and gas adsorption
Shi, Hongxia
Kong, Xiang-Jing
He, Tao
JOURNAL OF COORDINATION CHEMISTRY, 2020, 73 (05) : 844 - 853
[2] A Porous Cadmium(II) Framework: Synthesis, Crystal Structure, Gas Adsorption, and Fluorescence Sensing Properties
Zhou, Pingping
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2017, 643 (10): : 653 - 656
[3] Synthesis, Crystal Structure and Properties of a Nanotubular Metal-organic Framework (MOFs) Based on Cu(II) Oxide Chains and Benzenedicarboxylates
Xu Wen-Tao
Chen Lian
Jiang Fei-Long
Hong Mao-Chun
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (03) : 321 - 326
[4] Microporous Zinc(II) Metal-Organic Framework with 6-Connected pcu Topology: Synthesis, Structure, and Gas Adsorption Properties
Xing, Guang'en
Liu, Qifeng
Zhang, Yan
Zhang, Sufang
Dong, Yanli
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2015, 641 (8-9): : 1556 - 1559
[5] A microporous lanthanide metal-organic framework containing channels: Synthesis, structure, gas adsorption and magnetic properties
Li HuanHuan
Niu Zheng
Han Tian
Zhang ZhenJie
Shi Wei
Cheng Peng
SCIENCE CHINA-CHEMISTRY, 2011, 54 (09) : 1423 - 1429
[6] A microporous lanthanide metal-organic framework containing channels:Synthesis,structure,gas adsorption and magnetic properties
LI HuanHuan
Department of Chemistry
Science China Chemistry, 2011, (09) : 1423 - 1429
[7] A microporous lanthanide metal-organic framework containing channels:Synthesis,structure,gas adsorption and magnetic properties
LI HuanHuanNIU ZhengHAN TianZHANG ZhenJieSHI Wei CHENG Peng Key Laboratory of Advanced Energy Materials ChemistryMinistry of EducationMOE
Department of ChemistryNankai UniversityTianjin China
Science China(Chemistry), 2011, 54 (09) : 1423 - 1429
[8] A microporous lanthanide metal-organic framework containing channels: Synthesis, structure, gas adsorption and magnetic properties
HuanHuan Li
Zheng Niu
Tian Han
ZhenJie Zhang
Wei Shi
Peng Cheng
Science China Chemistry, 2011, 54 : 1423 - 1429
[9] A Porous Zn(II)-Metal-Organic Framework Constructed from Fluorinated Ligands for Gas Adsorption
Chen, Cheng-Xia
Wei, Zhang-Wen
Qiu, Qian-Feng
Fan, Yan-Zhong
Cao, Chen-Chen
Wang, Hai-Ping
Jiang, Ji-Jun
Fenske, Dieter
Su, Cheng-Yong
CRYSTAL GROWTH & DESIGN, 2017, 17 (04) : 1476 - 1479
[10] Solvothermal Synthesis and Crystal Structure of a Zn(II) Microporous Metal-organic Framework
Li Dong-Ping
Li Jing
Li Xu
Chen Ping-Hua
Jiao Xiao-Yan
Li Yong-Xiv
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 31 (11) : 1676 - 1680

← 1 2 3 4 5 →