The (P4HMes4)- Anion:: lability, fluxionality, and structural ambiguity (Mes=2,4,6-Me3C6H2)

被引：25

作者：

Wolf, Robert

Gomez-Ruiz, Santiago

Reinhold, Joachim

Boehlmann, Winfried

Hey-Hawkins, Evamarie

机构：

[1] Univ Leipzig, Inst Anorgan Chem, D-04103 Leipzig, Germany

[2] Univ Leipzig, Wilhelm Ostwald Inst Phys & Theoret, D-04103 Leipzig, Germany

[3] Univ Leipzig, Inst Expt Phys 2, D-04103 Leipzig, Germany

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 22期

关键词：

D O I：

10.1021/ic060795w

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and structural characterization of the tetramesityltetraphosphanide anion, (P(4)HMes(4))(-) (1), is described. It is shown that 1 partially decomposes in solution and displays an unsymmetrical structure in which, depending on conditions, the proton may or may not fluctuate between the terminal P atoms of the P-4 chain.

引用

页码：9107 / 9113

页数：7

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