Different role of H2S and dibenzothiophene in the incorporation of sulfur in the surface of bulk MoP during hydrodesulfurization

被引：43
|
作者：
Bai, Jin [1 ]
Li, Xiang [1 ,2 ]
Wang, Anjie [1 ,2 ]
Prins, Roel [3 ]
Wang, Yao [2 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
[2] Dalian Univ Technol, Liaoning Key Lab Petrochem Technol & Equipments, Dalian 116024, Peoples R China
[3] ETH, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland
来源：
JOURNAL OF CATALYSIS | 2013年 / 300卷
关键词：
Hydrodesulfurization; Molybdenum phosphide; H2S; Dibenzothiophene; Sulfur incorporation; METAL PHOSPHIDES; CATALYSTS; KINETICS; SILICA; SPECTROSCOPY; PERFORMANCE; NI2P; HDN;
D O I：
10.1016/j.jcat.2013.01.015
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The surface of MoP becomes sulfided during hydrodesulfurization (HDS) of dibenzothiophene (DBT), and the HDS activity increases with time on stream, showing that the sulfided MoP surface is more active than the fresh MoP surface. MoP pretreated with H2S/H-2 under HDS reaction conditions showed the same activity increase as fresh MoP, but XPS did not show any sulfur at the surface of the pretreated Mop. Hence, the sulfur that is incorporated into the MoP surface during the HDS of DBT originates from DBT rather than from H2S. (C) 2013 Elsevier Inc. All rights reserved.
引用
收藏
页码：197 / 200
页数：4
相关论文
共 50 条
  • [21] Dibenzothiophene hydrodesulfurization activity and surface sites of silica-supported MoP, Ni2P, and Ni-Mo-P catalysts
    Sun, FX
    Wu, WC
    Wu, ZL
    Guo, J
    Wei, ZB
    Yang, YX
    Jiang, ZX
    Tian, FP
    Li, C
    [J]. JOURNAL OF CATALYSIS, 2004, 228 (02) : 298 - 310
  • [22] Catalysts and Processes for H2S Conversion to Sulfur
    Barba, Daniela
    [J]. CATALYSTS, 2021, 11 (10)
  • [23] The diffusion coefficient of H2S in liquid sulfur
    Ji, Yiming
    Li, Haipeng
    Xu, Zhenghe
    Tan, Zhongchao
    [J]. FLUID PHASE EQUILIBRIA, 2011, 307 (02) : 135 - 141
  • [24] Catalysts and Processes for H2S Conversion to Sulfur
    Barba, Daniela
    [J]. CATALYSTS, 2021, 11 (08)
  • [25] CONTRIBUTIONS OF H2S TO ATMOSPHERIC SULFUR CYCLE
    JAESCHKE, W
    GEORGII, HW
    CLAUDE, H
    MALEWSKI, H
    [J]. PURE AND APPLIED GEOPHYSICS, 1978, 116 (2-3) : 465 - 475
  • [26] REACTION OF H2S AND SULFUR WITH LIMESTONE PARTICLES
    BORGWARDT, RH
    ROACHE, NF
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY PROCESS DESIGN AND DEVELOPMENT, 1984, 23 (04): : 742 - 748
  • [27] Studies on the Chemistry of H2S in Liquid Sulfur
    Clark, P. D.
    Lesage, K. L.
    Neufeld, A. K.
    Mason, A. J.
    [J]. Phosphorus, Sulphur and Silicon and the Related Elements, 1994, 93 (1-4):
  • [28] Selectivity and Stability Enhancement of Iron Oxide Catalyst by Ceria Incorporation for Selective Oxidation of H2S to Sulfur
    Koyuncu, D. D. Eslek
    Yasyerli, Sena
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2009, 48 (11) : 5223 - 5229
  • [29] SULFUR ISOTOPE COMPOSITION OF H2S EVOLVED DURING THE NONISOTHERMAL PYROLYSIS OF SULFUR-CONTAINING MATERIALS
    KROUSE, HR
    RITCHIE, RGS
    [J]. JOURNAL OF ANALYTICAL AND APPLIED PYROLYSIS, 1987, 12 (01) : 19 - 29
  • [30] H2S chemical looping selective and preferential oxidation to sulfur by bulk V2O5
    Kane, Tanushree
    Guerrero-Caballero, Jesus
    Lofberg, Axel
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2020, 265
12345