Octakis (9-anthracenylmethylthio) iron porphyrazine derivatives

被引：7
|
作者：
Gonca, Erguen [1 ]
机构：
[1] Fatih Univ, Dept Chem, TR-34500 Istanbul, Turkey
来源：
JOURNAL OF CHEMICAL RESEARCH-S | 2008年 / 08期
关键词：
anthracene; pyridine; pyrazine; shishkebab type oligomer; bisaxial complex;
D O I：
10.3184/030823408X340582
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Chloro[octakis(9-anthracenylmethylthio)porphyrazinato]iron(III), ([FePzCl]), was prepared by the reaction of metal-free porphyrazine with iron(II) acetate and further treatment with HCl solution. The monomeric bisaxial complex [FePz(py)(2)] as well as the bridged complex [FePz(pyz)](n) were formed as stable complexes by reacting [FePzCl] with pyridine or pyrazine, respectively. These novel complexes were characterised by elemental analysis, together with FT-IR, (1)H NMR, UV-Vis and mass spectral data.
引用
收藏
页码：465 / 467
页数：3
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