Graphene oxide modified non-noble metal electrode for alkaline anion exchange membrane water electrolyzers

被引:69
|
作者
Seetharaman, S. [1 ,2 ]
Balaji, R. [1 ]
Ramya, K. [1 ]
Dhathathreyan, K. S. [1 ]
Velan, M. [2 ]
机构
[1] Int Adv Res Ctr Powder Met & New Mat ARCI, Ctr Fuel Cell Technol, Chennai 600113, Tamil Nadu, India
[2] Anna Univ, Dept Chem Engn, AC Coll Technol, Chennai 600025, Tamil Nadu, India
关键词
Water electrolysis; Alkaline water electrolyzer; Anion exchange membrane; Graphene oxide; Hydrogen production; FUEL-CELLS; OXYGEN EVOLUTION; NICKEL; HYDROXIDE; HYDROGEN; TEMPERATURE; IONOMER; SHEETS; FILM;
D O I
10.1016/j.ijhydene.2013.09.033
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper reports the performance of a graphene oxide modified non noble metal based electrode in alkaline anion exchange water electrolyzer. The electrolytic cell was fabricated using a polystyrene based anion exchange membrane and a ternary alloy electrode of Ni as cathode and oxidized Ni electrode coated with graphene oxide as anode. The electro-chemical activity of the graphene oxide modified electrode was higher than the uncoated electrode. The anion exchange membrane water electrolyzer (AEMWE) with the modified electrode gave 50% higher current density at 30 degrees C with deionised water compared to that of an uncoated electrode at 2 V. Performance was found to increase with increase in temperature and with the use of alkaline solutions. The results of the solid state water electrolysis cell are promising method of producing low cost hydrogen. Copyright (C) 2013, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:14934 / 14942
页数:9
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