Study on Preparation of 1H,1H,2H-Heptadecafluorodecene

被引：0
|
作者：
Wang, Xiangcheng [1 ]
Chang, Geng [1 ]
Fu, AiQing
机构：
[1] Inst Chem Def, Beijing 102205, Peoples R China
来源：
ADVANCES IN CHEMICAL, MATERIAL AND METALLURGICAL ENGINEERING, PTS 1-5 | 2013年 / 634-638卷
关键词：
Perfluorooctyl Iodide; 1H; 2H; 2H-1Iodide-Perfluorodecane; Synthesis; 2H-Heptadecafluorodecene; HYDROSILYLATION;
D O I：
10.4028/www.scientific.net/AMR.634-638.2332
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
1H,1H,2H,2H-1Iodide-Perfluorodecane was synthesized use perfluorooctyl iodide and ethylene as materials, then reacted with sodium methoxide /methanol to gain 1H,1H,2H-Heptadecafluorodecene. Influence factors such as kinds of solvents, raw material configuration, concentration and time in the process of dehydrogen iodide were studied mainly. Optimization was using 1,1,2-Trichloro-1,2,2-trifluoroethane as solvent, sodium methoxide /methanol (2mol/L), 1H,1H,2H,2H-1Iodide-Perfluorodecane(M1): sodium methoxide(M2) =1:2, reacted 12 hours, the yield of 1H,1H,2H-Heptadecafluorodecene was up to 80%.
引用
收藏
页码：2332 / 2335
页数：4
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