Recent Progress in the Selective Oxidation of Sulfides with Hydrogen Peroxide

被引：10
|
作者：
Liu, Keyan [1 ]
Ou, Hui [1 ]
Shi, Xianying [1 ]
Dong, Xuefen [1 ]
Ma, Wenjuan [1 ]
Wei, Junfa [1 ]
机构：
[1] Shaanxi Normal Univ, Key Lab Macromol Sci Shaanxi Prov, Sch Chem & Chem Engn, Xian 710062, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 34卷 / 04期
基金：
中国国家自然科学基金;
关键词：
catalytic oxidation; sulfides; sulfones; sulfoxides; hydrogen peroxide; SULFUR ORGANIC-COMPOUNDS; ASYMMETRIC OXIDATION; CATALYZED OXIDATION; MILD OXIDATION; SOLVENT-FREE; ENANTIOSELECTIVE OXIDATION; CHEMOSELECTIVE OXIDATION; EFFICIENT CATALYST; REUSABLE CATALYST; HIGHLY EFFICIENT;
D O I：
10.6023/cjoc201310019
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Sulfoxides and sulfones have broad applications in pharmaceutical agents and pesticide due to their biologically activities and they are important synthetic intermediates in C C bond formation and various molecular rearrangements. The selective oxidation of sulfides is a straightforward and frequently used method to obtain sulfoxides and sulfones. Among various oxidizing agents, hydrogen peroxide as benign oxidant has attracted organic chemists' attention for a long time. This review summarizes the recent and important catalytic systems of metal and nonmetal in this area. The catalytic effect of different catalytic systems is briefly discussed herein.
引用
收藏
页码：681 / 692
页数：12
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