Composition Dependent Physicochemical Property Data for the Binary System Water and the Ionic Liquid 1-Butyl-3-methylimidazolium Methanesulfonate ([C4mim][MeSO3])

被引：22

作者：

Stark, Annegret ^{[2
]}

Zidell, Anthony W. ^{[1
]}

Russo, Joseph W. ^{[1
]}

Hoffmann, Markus M. ^{[1
]}

机构：

[1] SUNY Coll Brockport, Dept Chem, Brockport, NY 14420 USA

[2] Univ Leipzig, Inst Ind Chem, D-04107 Leipzig, Germany

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2012年 / 57卷 / 12期

基金：

美国国家科学基金会;

关键词：

DIFFUSION; SURFACE; AGGREGATION; INDICATOR; SOLUTES;

D O I：

10.1021/je300045c

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

A number of composition dependent physicochemical properties were measured for the water-[C(4)mim][MeSO3] binary system at 85 degrees C. Specifically, we provide data for density, heat capacity, heats of dissolution, conductivity, viscosity, as well as the self-diffusion coefficients of the cation, anion, and water. Ionic liquids based on the MeSO3 anion constitute a suitable medium for various chemistries. This study addresses the need to provide physicochemical data on [C(4)mim][MeSO3] and the water-[C(4)mim][MeSO3] binary systems that are currently unavailable. Additional analysis of the combined data is also presented to provide further insight into the molecular level behavior of the water-[C(4)mim][MeSO3] binary system.

引用

页码：3330 / 3339

页数：10

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