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Nitrogen-Doped Carbon Nanocages as Efficient Metal-Free Electrocatalysts for Oxygen Reduction Reaction
被引:712
|作者:
Chen, Sheng
[1
,2
]
Bi, Jiyu
[1
,2
]
Zhao, Yu
[1
,2
]
Yang, Lijun
[1
,2
]
Zhang, Chen
[1
,2
]
Ma, Yanwen
[3
]
Wu, Qiang
[1
,2
]
Wang, Xizhang
[1
,2
]
Hu, Zheng
[1
,2
]
机构:
[1] Nanjing Univ, Key Lab Mesoscop Chem MOE, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[2] Nanjing Univ, Jiangsu Prov Lab Nanotechnol, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China
[3] Nanjing Univ Posts & Telecommun, Jiangsu Key Lab Organ Elect & Informat Displays, Inst Adv Mat, Nanjing 210046, Jiangsu, Peoples R China
关键词:
metal-free electrocatalysts;
oxygen reduction reaction;
nitrogen-doped carbon nanocages;
high specific surface area;
fuel cells;
FUEL-CELL;
NANOTUBES;
CATALYST;
ELECTRODE;
GRAPHENE;
BORON;
D O I:
10.1002/adma.201202424
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Metal-free ORR Electrocatalysts: N-doped carbon nanocages (NCNCs) with large specific surface areas of up to 1393 m(2) g(-1), which demonstrate excellent ORR performance with high activity, are produced for the first time. Without the interference of any ORR-active metal impurities in NCNCs, the experimental results confirm that the ORR activity originates from the N-doped carbon species.
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页码:5593 / 5597
页数:5
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