Rationale on the standard enthalpies and entropies of formation of inorganic compounds and vaporisation of elements

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作者
Turkdogan, ET [1 ]
机构
[1] Pyromet & Thermochem, Pittsburgh, PA 15217 USA
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TF [冶金工业];
学科分类号
0806 ;
摘要
The standard enthalpies and entropies of metal halides, oxides, sulphides, nitrides, phosphides and hydrides are shown to conform to various types of regularities with respect to the stoichiometric ratios mol compound/mol gas X-2 and atomic mass of the metals. The entropies of vaporisation of most elements are shown to be a simple function of temperature at the boiling and 1 atm vapour pressure.
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页码:471 / 478
页数:8
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