Effect of pyrolysis temperature and catalyst on production of bio-oil and bio-char from avocado seeds

被引:33
|
作者
Durak, Halil [1 ]
Aysu, Tevfik [2 ]
机构
[1] Yuzuncu Yil Univ, Vocat Sch Hlth Serv, TR-65080 Van, Turkey
[2] Yuzuncu Yil Univ, Dept Chem, Fac Educ, TR-65080 Van, Turkey
关键词
Catalysis; Bio-energy; Pyrolysis; Bio-oil; Bio-char; Persea americana; SAFFLOWER SEED; HEATING RATE; LIQUID FUEL; BIOMASS; LIQUEFACTION; SLOW; EXTRACTION; RESIDUES; SOLVENTS; KINETICS;
D O I
10.1007/s11164-014-1878-0
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The slow pyrolysis of avocado seeds (Persea americana) was performed in a fixed-bed tubular reactor with (KOH, Al2O3) and without a catalyst, at three temperatures ranging from 400 to 600 A degrees C, with heating rates of 50 A degrees C/min. The amounts of bio-char, bio-oil and gas produced, as well as the compositions of the resulting bio-oils, were determined by GC-MS and FT-IR. The influences of pyrolysis parameters, such as temperature and catalysts, on product yields were subsequently investigated. Both temperature and catalysts were determined to be the main factors affecting the conversion (liquid+gas products) of avocado seeds into solid, liquid and gaseous products. The highest liquid yield (37.5 %) including water was obtained using 10 % KOH catalyst at 600 A degrees C at a heating rate of 50 A degrees C/min when employing 0.224 > Dp > 0.150 mm particle size raw material and a 100 cm(3)/min sweeping gas flow rate.
引用
收藏
页码:8067 / 8097
页数:31
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