Microwave-Assisted Click Chemistry Synthesis of 1,2,3-Triazoles from Aryldiazonium Silica Sulfates in Water

被引：15

作者：

Zarei, Amin ^{[1
]}

Khazdooz, Leila ^{[2
]}

Hajipour, Abdol R. ^{[3
,4
]}

Aghaei, Hamidreza ^{[5
]}

Azizi, Ghobad ^{[4
]}

机构：

[1] Islamic Azad Univ, Fasa Branch, Dept Sci, Fasa 7461713591, Fars, Iran

[2] Islamic Azad Univ, Khorasgan Branch, Dept Sci, Esfahan 81595158, Iran

[3] Isfahan Univ Technol, Coll Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

[4] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA

[5] Islamic Azad Univ, Shahreza Branch, Dept Chem, Shahreza 31186145, Isfahan, Iran

来源：

SYNTHESIS-STUTTGART | 2012年 / 44卷 / 21期

关键词：

aryldiazonium silica sulfates; click reaction; 1,2,3-triazoles; microwave irradiation; ONE-POT SYNTHESIS; AZIDE-ALKYNE CYCLOADDITION; SOLVENT-FREE CONDITIONS; SITU GENERATED AZIDES; 1,4-DISUBSTITUTED 1,2,3-TRIAZOLES; COPPER NANOPARTICLES; TERMINAL ALKYNES; 1,3-DIPOLAR CYCLOADDITIONS; REUSABLE CATALYST; SUPPORTED COPPER(I);

D O I：

10.1055/s-0032-1316783

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A microwave-assisted click chemistry synthesis of 1,4-disubstituted 1,2,3-triazoles is studied by in situ generation of aryl azides via the reaction of aryldiazonium silica sulfates and sodium azide, followed by coupling with a terminal alkyne in the presence of copper catalyst. These reactions are carried out in water under mild and heterogeneous conditions without using any additional ligands.

引用

页码：3353 / 3360

页数：8

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