Synthesis, spectral and electrochemical study of coordination molecules Cu4OX6L4: 4-cyanopyridine Cu4OBr n Cl(6-n)(4-CNpy)4 complexes

被引：4

作者：

Ondrejovic, Gregor ^{[1
]}

Kotocova, Adela ^{[1
]}

Koman, Marian ^{[1
]}

Segl'a, Peter ^{[1
]}

机构：

[1] Slovak Tech Univ Bratislava, Inst Inorgan Chem Technol & Mat, Fac Chem & Food Technol, SK-81237 Bratislava, Slovakia

来源：

CHEMICAL PAPERS | 2010年 / 64卷 / 03期

关键词：

copper(II) 4-cyanopyridine complexes; donor-acceptor vibrational coupling; electronic spectra; electrochemistry; pi-back bonding; SUBSTITUTED PYRIDINE DERIVATIVES; INFRARED-SPECTRA; ELECTRONIC-STRUCTURES; VIBRATIONAL-SPECTRA; METAL COMPLEXES; LIGAND; DONOR; RINGS; BOND;

D O I：

10.2478/s11696-010-0015-9

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New 4-cyanopyridine halide and mixed-halide Cu4OBr (n) Cl(6-n)(4-CNpy)(4) complexes (4-CNpy = 4-cyanopyridine, n = 0-6) were synthesised, characterised, and studied by infrared spectra, electronic spectra, and cyclic voltammetry. Infrared spectra revealed donor-acceptor vibrational couplings of the Cu4O, Cu-Cl, and Cu-N stretching vibrations with the in-plane and out-of-plane pyridine ring vibrations. The infrared spectra, electronic spectra, and half-wave potentials correspond to a weak donor and a strong acceptor behaviour of the 4-cyanopyridine ligands and to pi-back bonding, Cu(II)-> pyridine rings. The results were compared with the related pyridine and 4-substituted pyridine complexes.

引用

页码：329 / 338

页数：10

共 50 条

[41] Synthesis and Characterization of (Et4N)4[MoS4Cu16Cl12]: A Polynuclear Molybdenum-Copper Cluster Containing a Central Tetrahedral MoS4 Encapsulated by Octahedral Cu6 and Tetrahedral Cu4 Arrays
Inorg Chem, 4 (1080):
[42] Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2
Wang, Hong
Lu, Bin
Zhao, Jingxiang
Cai, Qinghai
JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (07) : 1261 - 1265
[43] Ionothermal synthesis and structural characterization of [Cu(C4H6N2)4]Br2 and [Ni(C4H6N2)4]Br2
HONG WANG
BIN LU
JINGXIANG ZHAO
QINGHAI CAI
Journal of Chemical Sciences, 2015, 127 : 1261 - 1265
[44] Tetranuclear Copper(II) Complexes Bearing Cu4O6 and Cu4O4 Cores: Synthesis, Structure, Magnetic Properties, and DFT Study
Banerjee, Atanu
Singh, Reena
Mondal, Pallab
Colacio, Enrique
Rajak, Kajal Krishna
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (05) : 790 - 798
[45] SYNTHESIS AND CRYSTAL-STRUCTURES OF TETRANUCLEAR AND HEXANUCLEAR COPPER(I) COMPLEXES OF PYRIMIDINE-DERIVATIVES, [CU4(C4H8N2S)4](CLO4)4 AND [CU6(C5H5N2S)6]
KITAGAWA, S
NOZAKA, Y
MUNAKATA, M
KAWATA, S
INORGANICA CHIMICA ACTA, 1992, 197 (02) : 169 - 175
[46] Synthesis, crystal structure of a zigzag cluster coordination polymer {(n-Bu4N)2[Mo2O2S6Cu6Br4(4,4′-bipy)3]•0.5H2O}n
Liang Kai
Ji Ya-Li
Xian Chun-Ying
Li Yi-Zhi
Zheng He-Gen
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2008, 24 (09) : 1543 - 1545
[47] STRUCTURE OF TETRAKIS(N-METHYLIMIDAZOLE-N')COPPER(I) PERCHLORATE, [CU(C4H6N2)4].[CLO4]
CLEGG, W
ACOTT, SR
GARNER, CD
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1984, 40 (MAY) : 768 - 769
[48] SYNTHESIS AND PROPERTIES OF TETRANUCLEAR OCTAHALO COPPER(II) COMPLEXES, N4CU4X8 (N = N, N-DIETHYLNICOTINAMIDE, X = CL, BR OR I), AND TRANSMETALATION OF N4CU4CL8 WITH NI(NS)2, (NS = S-METHYL ISOPROPYLIDENEHYDRAZINECARBOTHIOATE) IN APROTIC MEDIA
ELSAYED, MA
POLYHEDRON, 1992, 11 (10) : 1261 - 1267
[49] Greasy tails switch 1D-coordination[{Zn2( OAc)4(4′-(4-ROC6H4)-4,2′:6′,4"-tpy)}n] polymers to discrete [Zn2(OAc)4(4′-(4-ROC6H4)-4,2′:6′,4"-tpy)2] complexes
Klein, Y. Maximilian
Constable, Edwin C.
Housecroft, Catherine E.
Zampese, Jennifer A.
Crochet, Aurelien
CRYSTENGCOMM, 2014, 16 (42): : 9915 - 9929
[50] TETRAGONAL VS TRIGONAL COORDINATION IN COPPER(II) COMPLEXES WITH TRIPOD LIGANDS - STRUCTURES AND PROPERTIES OF [CU(C21H24N4)CL]PF6 AND [CU(C18H18N4)CL]PF6
KARLIN, KD
HAYES, JC
JUEN, S
HUTCHINSON, JP
ZUBIETA, J
INORGANIC CHEMISTRY, 1982, 21 (11) : 4106 - 4108

← 1 2 3 4 5 →