Catalytic C-C coupling reactions

被引：0

作者：

Blaser, Hans-Ulrich ^{[1
]}

Pugin, Benoit ^{[1
]}

Spielvogel, Dirk ^{[1
]}

机构：

[1] Solvias AG, CH-4002 Romerweg, Kaiseraugst, Switzerland

来源：

CHIMICA OGGI-CHEMISTRY TODAY | 2011年 / 29卷 / 05期

关键词：

NOBEL Prize 2010; Pd catalysis; C-C coupling reactions; phosphine ligands; industrial research; HECK REACTION; HOMOGENEOUS CATALYSIS; PALLADIUM; COMPLEXES;

D O I：

暂无

中图分类号：

Q81 [生物工程学（生物技术）]; Q93 [微生物学];

学科分类号：

071005 ; 0836 ; 090102 ; 100705 ;

摘要：

After a short description of the achievements of the three Nobel laureates, R&D issues for the application of Pd coupling reactions in the fine chemicals industry are discussed. In a first part, some background is given on industrial R&D and the role of coupling for preparative applications is described. Thematic approaches to industrial R&D are described and two of these are illustrated with relevant examples from the literature and from our own laboratories: i) Development of catalytic systems with very high turnover numbers; ii) Catalysts and ligands for coupling reactions with aryl chlorides. Finally, four selected Pd catalyzed production processes are briefly described.

引用

页码：42 / 44

页数：3

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