Study on the spin probe added polymeric dense membranes by 13C solid-state nuclear magnetic resonance spectroscopy

被引：6

作者：

Rana, D ^{[1
]}

Matsuura, T ^{[1
]}

Khulbe, KC ^{[1
]}

Feng, C ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem Engn, Ind Membrane Res Inst, Ottawa, ON K1N 6N5, Canada

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2006年 / 99卷 / 06期

关键词：

TEMPO free radical; C-13 solid-state CPMAS NMR; cellulose acetate; poly(2,6-dimethyl-1,4-phenylene oxide); dense polymeric membrane;

D O I：

10.1002/app.22908

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dense cellulose acetate, CA, and poly(2,6dimethyl-1,4-phenylene oxide), PPO, membranes were prepared with and without blending a spin probe, TEMPO free radical, and their C-13 solid-state cross-polarization magic angle spinning nuclear magnetic resonance, CPMAS NMR, spectra were taken. It was observed that there was no effect of blending TEMPO on the CPMAS NMR spectra of CA and PPO membranes. It was concluded that there was no chemical or physical interaction between the polymeric material and TEMPO. (c) 2006 Wiley Periodicals, Inc.

引用

页码：3062 / 3069

页数：8

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