Structure-induced luminescence and bioactivities of Zinc(II) complexes with 2-(2,4-dichlorophenoxy)-N?-[pyridin-2-ylmethylene]acetohydrazide

被引：4
|
作者：
Gusev, Alexey [1 ]
Braga, Elena [1 ]
Karmazina, Alexandra [1 ]
Karmazin, Andrey [1 ]
Konnik, Oleg [1 ]
Kiskin, Mikhail [2 ]
Baryshnikov, Glib [3 ]
Linert, Wolfgang [4 ]
机构：
[1] VI Vernadsky Crimean Fed Univ, Simferopol 295007, Crimea, Russia
[2] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[3] Linkoping Univ, Dept Sci & Technol, Lab Organ Elect, SE-60174 Norrkoping, Sweden
[4] Vienna Univ Technol, Inst Appl Phys, Wiedner Hauptstr 8-10, A-1040 Vienna, Austria
来源：
INORGANICA CHIMICA ACTA | 2023年 / 551卷
关键词：
Zn complex; Hydrazone; 4-D; Crystal structure; Luminescence; Bioactivities; EXCITATION-DEPENDENT EMISSION; SCHIFF-BASE; ZN(II) COMPLEXES; PHOTOLUMINESCENCE; CRYSTAL; LIGANDS;
D O I：
10.1016/j.ica.2023.121481
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The structure and photophysical properties of the series of Zn(II) complex with the hydrazone ligand, 2-(2,4dichlorophenoxy)-N '-[1-pyridin-2-ylmethylene]acetohydrazide, and different counter anions have been synthesized and characterized by single crystal X-ray diffraction, FT-IR, elemental analyses and ESI-MS. X-ray crystallography has proved the neutral or monoanionic form of ligand upon coordination. All complexes are mononuclear with the tetra/penta/hexacoordinated zinc atoms. The diverse supramolecular architectures of the complexes show that counter-anions have significant impacts on the structures. Furthermore DFT, luminescence properties, antibacterial and herbicide activities of the complexes have been investigated were carried out as well.
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页数：10
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