Some Remarks on the Boundary of Thermodynamic Stability

被引:2
|
作者
Toikka, Alexander [1 ]
Misikov, Georgii [1 ]
Toikka, Maria [1 ]
机构
[1] St Petersburg State Univ, Dept Chem Thermodynam & Kinet, Univ pr 26, St Petersburg 198504, Russia
基金
俄罗斯科学基金会;
关键词
stability conditions; boundary of stability; neutral equilibrium; Gibbs-Duhem equation;
D O I
10.3390/e25070969
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
In this paper, we have considered some elements of the classical phenomenological theory of thermodynamic stability, which seem controversial and ambiguous. The main focus is on the conditions of the stability boundary; a new version of the derivation of the relations defining the specified boundary is proposed. Although the final results, in general, coincide with the classical relations, the described approach, from our point of view, provides a clearer and more accurate idea of the stability conditions and their boundaries.
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页数:6
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