Hydrogenation of Lignocellulosic Biomass-Derived Furfural over Ruthenium and Nickel Catalysts Supported on Mesoporous Aluminosilicate

被引：1
|
作者：
Roldugina, E. A. [1 ]
Boronoev, M. P. [1 ]
Shakirov, I. I. [1 ]
Kardasheva, Yu. S. [1 ]
Kardashev, S. V. [1 ]
Maximov, A. L. [1 ,2 ]
Karakhanov, E. A. [1 ]
机构：
[1] Lomonosov Moscow State Univ, Fac Chem, Moscow 119991, Russia
[2] Russian Acad Sci, Topchiev Inst Petrochem Synth, Moscow 119991, Russia
来源：
PETROLEUM CHEMISTRY | 2023年 / 63卷 / 06期
基金：
俄罗斯科学基金会;
关键词：
hydrogenation; furfural; mesoporous aluminosilicates; ruthenium; nickel; SELECTIVE HYDROGENATION;
D O I：
10.1134/S0965544123040072
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The paper describes synthesis of ruthenium and nickel catalysts supported on aluminum-modified SBA-15 (Santa Barbara Amorphous-15) mesoporous silicate, designated as Al-SBA-15, with a Si/Al ratio of 20. The catalysts were investigated in aqueous-phase hydrogenation of furfural, a valuable product obtained from lignocellulosic biomass. Elevating the reaction temperature from 200 to 250 & DEG;C and the hydrogen pressure from 3 to 5 MPa enhanced the selectivity towards methyltetrahydrofuran (MTHF). The ruthenium catalyst outperformed its nickel counterpart in terms of activity in aqueous-phase furfural hydrogenation (250 & DEG;C, 5 MPa H2).
引用
收藏
页码：655 / 662
页数：8
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