Uranium ions in the sesquinitride alpha-U2N3 occupy independent acentric and centrosymmetric sites according to conventional x-ray diffraction patterns [R. Troc ', J. Solid State Chem. 13, 14 (1975)]. We submit that polar uranium multipoles in acentric sites are revealed in resonant x-ray diffraction data recently published by Lawrence Bright et al. [Phys. Rev. B 100, 134426 (2019)]. To this end, their diffraction data gathered with a primary x-ray energy in the vicinity of the uranium M4 absorption edge are compared to symmetry-informed diffraction amplitudes calculated for the bixbyite alpha-Mn2O3lattice structure. Bragg spots forbidden in this lattice diffraction pattern appear to provide clear-cut evidence for high-order polar uranium multipoles.
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Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USAUniv Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
Brown, Jessie L.
Wu, Guang
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Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USAUniv Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
Wu, Guang
Hayton, Trevor W.
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Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USAUniv Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics
严小松
刘荣
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics
刘荣
鹿心鑫
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics
鹿心鑫
蒋励
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics
蒋励
温中伟
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics
温中伟
韩子杰
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Institute of Nuclear Physics and Chemistry, China Academy of Engineering PhysicsInstitute of Nuclear Physics and Chemistry, China Academy of Engineering Physics