Liquid-Liquid Equilibria of Green and Biobased Solvents 2-Methyltetrahydrofuran plus (Ethanol or 1-Butanol) + Water and Cyclopentyl-methyl-ether plus (Ethanol or 1-Butanol) + Water at 298.15 K

被引:1
|
作者
Buchweitz, Vanessa [1 ]
Peng, Daili [1 ]
Minceva, Mirjana [1 ]
机构
[1] Tech Univ Munich, TUM Sch Life Sci, Dept Life Sci Engn, Biothermodynam, D-85354 Freising Weihenstephan, Germany
来源
关键词
CYCLOPENTYL METHYL-ETHER; TERNARY-SYSTEMS; LIPID EXTRACTION; LLE MEASUREMENTS; WATER; QUATERNARY;
D O I
10.1021/acs.jced.3c00673
中图分类号
O414.1 [热力学];
学科分类号
摘要
Green and biobased solvents are gaining increased interest as possible alternatives to organic solvents in multiple processes. The knowledge of liquid-liquid equilibria (LLE) of systems containing these groups of solvents is necessary for designing greener processes with biphasic liquid systems. In this study, the LLE values of the systems 2-methyltetrahydrofuran + ethanol + water, 2-methyltetrahydrofuran +1-butanol + water, cyclopentyl-methyl-ether + ethanol + water, and cyclopentyl-methyl-ether +1-butanol + water were measured at 298.15 K and 101.3 kPa. The experimental LLE data were successfully correlated to the nonrandom two-liquid model.
引用
收藏
页码:1124 / 1130
页数:7
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