Mixed-Alkali Effect on Thermal Property and Elastic Behavior in Borosilicate Glasses

被引：0

作者：

Xie, Xianmao ^{[1
]}

Zhou, Hemin ^{[1
]}

Ke, Xuefei ^{[1
]}

Wang, Xiaowei ^{[2
]}

Wang, Yadan ^{[2
]}

Zhang, Jiayan ^{[1
]}

Qiao, Ang ^{[1
,3
]}

Tao, Haizheng ^{[1
]}

机构：

[1] Wuhan Univ Technol, State Key Lab Silicate Mat Architectures, Wuhan 430070, Peoples R China

[2] AVIC Jonhon Optron Technol Co Ltd, Luoyang 471003, Peoples R China

[3] Wuhan Univ Technol, Adv Engn Technol Res Inst Zhongshan City, Zhongshan 528437, Peoples R China

来源：

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2023年 / 38卷 / 05期

基金：

中国国家自然科学基金;

关键词：

mixed-alkali effect; borosilicate glass; elastic response to temperature; structural origin; STRUCTURAL-CHANGES; SODIUM;

D O I：

10.1007/s11595-023-2790-5

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

We investigated the mixed alkali effect on the thermal properties and elastic response to temperature in the borosilicate glasses system with the composition of 70.65SiO2 center dot 21.09B2O3 center dot 1.88Al2O3 center dot(6.3 8- x)Li2O center dot xNa2O glasses, where x = 0.00, 1.595, 3.19, 4.785, and 6.38. Except for the expected positive and negative deviations from linearity for the coefficients of thermal expansion, room temperature E and G, we observed a new mixed alkali effect on the response of elastic moduli to temperature. Fourier transform infrared spectra were obtained to elucidate the possible structural origin of the mixed alkali effects. This work provides a valuable insight into the structural and mechanical properties of mixed-alkali borosilicate glasses.

引用

页码：1017 / 1024

页数：8

共 50 条

[21] Stretched exponential relaxation of glasses: Origin of the mixed-alkali effect
Yu, Yingtian
Mauro, John C.
Bauchy, Mathieu
[J]. AMERICAN CERAMIC SOCIETY BULLETIN, 2017, 96 (04): : 34 - 36
[22] INFRARED SPECTROSCOPIC STUDY OF MIXED-ALKALI EFFECT IN BORATE GLASSES
SELVARAI, U
RAO, KJ
[J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1984, 40 (11-1): : 1081 - 1085
[23] INTERNAL FRICTION OF MIXED-ALKALI SILICATE GLASSES
STEINKAMP, WE
SHELBY, JE
DAY, DE
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1967, 50 (05) : 271 - +
[24] Structure and rheological behavior of mixed-alkali molybdate and tungstate glasses and liquids
Lovi, Jacob
Sen, Sabyasachi
[J]. Journal of Non-Crystalline Solids, 2024, 639
[25] Electrical conductivity of mixed-alkali fluorozirconate glasses
N. V. Gur’ev
G. T. Petrovskii
A. A. Pronkin
[J]. Glass Physics and Chemistry, 2000, 26 (5) : 435 - 440
[26] POLARIZATION AND CONDUCTION MECHANISM IN MIXED-ALKALI GLASSES
AGARWAL, AK
DAY, DE
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1982, 65 (05) : 231 - 237
[27] VOLUME CHANGES IN MIXED-ALKALI SILICATE GLASSES
CAPORALI, RV
[J]. JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1964, 47 (08) : 412 - 413
[28] Cation sites in mixed-alkali phosphate glasses
Wenslow, RM
Mueller, KT
[J]. JOURNAL OF NON-CRYSTALLINE SOLIDS, 1998, 231 (1-2) : 78 - 88
[29] Diffusion in single and mixed-alkali borate glasses
Schoo, U
Cramer, C
Ratai, E
Mehrer, H
[J]. DIFFUSIONS IN MATERIALS: DIMAT2000, PTS 1 & 2, 2001, 194-1 : 925 - 933
[30] Electrical conductivity of mixed-alkali fluorozirconate glasses
Gur'ev, NV
Petrovskii, GT
Pronkin, AA
[J]. GLASS PHYSICS AND CHEMISTRY, 2000, 26 (05) : 435 - 440

← 1 2 3 4 5 →