Crystal structures of the isotypic complexes bis(morpholine)gold(I) chloride and bis(morpholine)gold(I) bromide

被引：2
|
作者：
Doering, Cindy [1 ]
Jones, Peter G. [1 ]
机构：
[1] Tech Univ Carolo Wilhelmina Braunschweig, Inst Anorgan & Analyt Chem, Hagenring 30, D-38106 Braunschweig, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2023年 / 79卷
关键词：
crystal structure; gold; morpholine; secondary interactions; GOLD(I) COMPLEXES; AMINE LIGANDS; NETWORKS;
D O I：
10.1107/S2056989023009702
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The compounds bis(morpholine-kappa N)gold(I) chloride, [Au(C4H9NO)(2)]Cl, 1, and bis(morpholine-kappa N)gold(I) bromide, [Au(C4H9NO)(2)]Br, 2, crystallize isotypically in space group C2/c with Z = 4. The gold atoms, which are axially positioned at the morpholine rings, lie on inversion centres (so that the N-Au-N coordination is exactly linear) and the halide anions on twofold axes. The residues are connected by a classical hydrogen bond N-H center dot center dot center dot halide and by a short gold center dot center dot center dot halide contact to form a layer structure parallel to the bc plane. The morpholine oxygen atom is not involved in classical hydrogen bonding.
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收藏
页码：1161 / +
页数：11
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