Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2

被引：0

作者：

Liu, Changyou ^{[1
]}

Hou, Ketian ^{[1
]}

Zhang, Bei ^{[1
]}

机构：

[1] Xinjiang Univ, Sch Phys Sci & Technol, Urumqi 830046, Xinjiang, Peoples R China

来源：

RESULTS IN PHYSICS | 2024年 / 57卷

基金：

中国国家自然科学基金;

关键词：

UV; Birefringence; Nitrate optical materials; LARGE 2ND-HARMONIC GENERATION; BIREFRINGENCE; CRYSTAL; ENHANCEMENT; PEROVSKITE; ANISOTROPY; FLUORIDE; GROWTH;

D O I：

10.1016/j.rinp.2024.107340

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Two new nitrates Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2 have been synthesized by hydrothermal method, and they are crystallized in orthorhombic space group Pnma (no. 62) and tetragonal space group P4/mnc (no. 128), respectively. ZnCl4 and RbO3Cl6 polyhedron, NaO4Cl2 and RbO8Cl2 polyhedron are connected by sharing O or Cl atoms to construct three-dimensional (3D) frameworks with trigonal plane NO3 units as pseudo-layers, in which different types of channels are presented. In addition, Rb5Na(NO3)4Cl2 exhibits a perovskite-related framework, and Rb3ZnNO3Cl4 crystals is grown with dimensions up to 5x4.5x1 mm3. Notably, these two compounds have short UV cut-off edge (below 222 nm and 238 nm, respectively). Theoretical calculations indicate that the birefringence enhancement is mainly derived from pi-conjugated NO3 units.

引用

页数：5

共 50 条

[31] NEGATIVE ISOTOPE EFFECT OF PHASE-TRANSITION 2-3 IN (NH4,CS)CL AND (NH4,RB)CL
BRAUER, P
JAHN, IR
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES, 1978, 33 (09): : 1093 - 1094
[32] Hydrogen-bonded coordination network in crystal structures of [Cu(3-PM)4Cl2] and [Cu(4-PM)4Cl]Cl, (PM = pyridylmethanol)
Jan Moncol
Marcela Mudra
Peter Lonnecke
Marian Koman
Milan Melnik
Journal of Chemical Crystallography, 2004, 34 : 423 - 431
[33] Hydrogen-bonded coordination network in crystal structures of [Cu(3-PM)4Cl2] and [Cu(4-PM)4Cl]Cl, (PM = pyridylmethanol)
Moncol, J
Mudra, M
Lonnecke, P
Koman, M
Melnik, M
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (07) : 423 - 431
[34] Two-dimensional tetramer-cuprate Na5RbCu4(AsO4)4Cl2:: phase transitions and AFM order as seen by 87Rb NMR
Stern, R
Heinmaa, I
Kriisa, A
Joon, E
Vija, S
Clayhold, J
Ulutagay-Kartin, M
Mo, X
Queen, W
Hwu, SJ
PHYSICA B-CONDENSED MATTER, 2006, 378-80 : 1124 - 1125
[35] New quaternary selenoantimonates AHgSbSe3 (A = Rb, Cs) synthesis, structures and optical properties
Chen, Z
Wang, RJ
Li, J
SOLID-STATE CHEMISTRY OF INORGANIC MATERIALS II, 1999, 547 : 419 - 424
[36] A new class of hybrid materials via salt inclusion: Novel copper(II) arsenates Na5ACu4(AsO4)4Cl2 (A = Rb, Cs) composed of alternating covalent and ionic lattices
Hwu, Shiou-Jyh
Ulutagay-Kartin, Mutlu
Clayhold, Jeffrey A.
Mackay, Richard
Wardojo, Tina A.
O'Connor, Charles J.
Krawiec, Mariusz
Journal of the American Chemical Society, 2002, 124 (42): : 12404 - 12405
[37] Synthesis and properties of puninite-type A2Cu3O(SO4)3 (A = Na, K, Rb, Cs) sulfate materials
Nekrasova, Diana
Chen, Zhuici
Kovrugin, Vadim
Mentre, Olivier
Colmont, Marie
Siidra, Oleg
ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2018, 74 : E265 - E265
[38] A new class of hybrid materials via salt inclusion:: Novel copper(II) arsenates Na5ACu4(AsO4)4Cl2 (A = Rb, Cs) composed of alternating covalent and ionic lattices
Hwu, SJ
Ulutagay-Kartin, M
Clayhold, JA
Mackay, R
Wardojo, TA
O'Connor, CJ
Krawiec, M
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (42) : 12404 - 12405
[39] Synthesis and crystal structure of alkali metal and ammonium nitratocuprates(II):: M3[Cu(NO3)4](NO3) (M = K, NH4, Rb) and CS2[CU(NO3)4]
Morozov, IV
Fedorova, AA
Troyanov, SI
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1998, 624 (09): : 1543 - 1547
[40] AMMONIATION, ACID DISSOCIATION, AND HYDROGEN-EXCHANGE OF [CO(NH3)5CL]2+ AND CIS-[CO(NH3)4CL2]+ AND TRANS-[CO(NH3)4CL2]+ IN LIQUID-AMMONIA
BALT, S
GAMELKOORN, HJ
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (12) : 3596 - 3600

← 1 2 3 4 5 →