Synthesis, structures and properties of two new nitrate optical materials: Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2

被引：0

作者：

Liu, Changyou ^{[1
]}

Hou, Ketian ^{[1
]}

Zhang, Bei ^{[1
]}

机构：

[1] Xinjiang Univ, Sch Phys Sci & Technol, Urumqi 830046, Xinjiang, Peoples R China

来源：

RESULTS IN PHYSICS | 2024年 / 57卷

基金：

中国国家自然科学基金;

关键词：

UV; Birefringence; Nitrate optical materials; LARGE 2ND-HARMONIC GENERATION; BIREFRINGENCE; CRYSTAL; ENHANCEMENT; PEROVSKITE; ANISOTROPY; FLUORIDE; GROWTH;

D O I：

10.1016/j.rinp.2024.107340

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Two new nitrates Rb3ZnNO3Cl4 and Rb5Na(NO3)4Cl2 have been synthesized by hydrothermal method, and they are crystallized in orthorhombic space group Pnma (no. 62) and tetragonal space group P4/mnc (no. 128), respectively. ZnCl4 and RbO3Cl6 polyhedron, NaO4Cl2 and RbO8Cl2 polyhedron are connected by sharing O or Cl atoms to construct three-dimensional (3D) frameworks with trigonal plane NO3 units as pseudo-layers, in which different types of channels are presented. In addition, Rb5Na(NO3)4Cl2 exhibits a perovskite-related framework, and Rb3ZnNO3Cl4 crystals is grown with dimensions up to 5x4.5x1 mm3. Notably, these two compounds have short UV cut-off edge (below 222 nm and 238 nm, respectively). Theoretical calculations indicate that the birefringence enhancement is mainly derived from pi-conjugated NO3 units.

引用

页数：5

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