Metal-Free Aerobic C-N Bond Formation of Styrene and Arylamines via Photoactivated Electron Donor-Acceptor Complexation

被引：1
|
作者：
Fan, Duona [1 ]
Sabri, Ahmed [1 ]
Sasai, Hiroaki [1 ]
Takizawa, Shinobu [1 ]
机构：
[1] Osaka Univ, SANKEN, Ibaraki, Osaka 5670047, Japan
来源：
MOLECULES | 2023年 / 28卷 / 01期
关键词：
hydroamination; photocatalyst-free; UV light; C-N functionalization; photoactivation; INTERMOLECULAR HYDROAMINATION; CATALYZED HYDROAMINATION; ALKENES; AMINES; AMINATION; ANILINES; HYDROARYLATION;
D O I：
10.3390/molecules28010356
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
This study processes a facile and green approach for the Markovnikov-selective hydroamination of styrene with naphthylamine through irradiation with UV LED light (365 nm) via an electron donor-acceptor complexation between naphthylamines and oxygen in situ. This protocol showcases the synthetic potential for aerobic C-N bond formation without using a metal catalyst and photosensitizer. Three naphthylamines were examined and afforded desired C-N bond formation product in moderate yield.
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页数：10
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