Cp2TiCl2-Catalyzed cycloboration of monoterpene methylene derivatives with BF3 <middle dot> THF

被引：1
|
作者：
Tulyabaeva, L. I. [1 ]
Salakhutdinov, R. R. [1 ]
Tyumkina, T. V. [1 ]
Tulyabaev, A. R. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prosp Oktyabrya, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 10期
关键词：
monoterpenes; (-)-beta-pinene; (-)-camphene; L(-)-menthol; cycloboration; spiroboracarbocycles; BF3 center dot THF; Cp2TiCl2; ALPHA-OLEFINS; HYDROBORATION;
D O I：
10.1007/s11172-023-4046-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1-Fluorine-substituted spiroboracarbocycles were first synthesized by cycloboration of monoterpenes ((-)-beta-pinene, (-)-camphene, and L(-)-menthol methylene derivative) with boron trifl uoride (BF3 center dot THF) in the presence of two-component catalytic system Cp2TiCl2/Mg in tetrahydrofuran.
引用
收藏
页码：2446 / 2452
页数：7
相关论文
共 50 条
  • [21] BF3<middle dot>OEt2 Catalyzed Cascade [4+2] Benzannulation of Vinyloxiranes with Coumarins to Construct Benzocoumarin Derivatives
    Wang, Yafei
    Wang, Yujia
    Qu, Jiaxin
    Yang, Tongtong
    Zhang, Yining
    Yuan, Chunhao
    Guo, Hongchao
    Wang, Chang
    JOURNAL OF ORGANIC CHEMISTRY, 2024, 89 (13): : 9462 - 9472
  • [22] Cp2TiCl2-catalyzed highly regioselective hydro-amination of styrenes with hydroxylamines
    Luo, Xuewei
    Wang, Sheng
    Xi, Chanjuan
    ORGANIC CHEMISTRY FRONTIERS, 2018, 5 (07): : 1184 - 1187
  • [23] Cp2TiCl2-catalyzed hydrocarboxylation of alkynes with CO2: formation of α,β-unsaturated carboxylic acids
    Shao, Peng
    Wang, Sheng
    Du, Gaixia
    Xi, Chanjuan
    RSC ADVANCES, 2017, 7 (06): : 3534 - 3539
  • [24] CP2TICL2-CATALYZED HYDROMAGNATION OF DISUBSTITUTED ACETYLENES AS A STEREOSPECIFIC ROUTE TO Z-ALKENES
    DZHEMILEV, UM
    VOSTRIKOVA, OS
    SULTANOV, RM
    GIMAEVA, AR
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1988, 37 (09): : 1936 - 1939
  • [25] Oxysulfonylation of Alkynes with Sodium Sulfinates to Access β-Keto Sulfones Catalyzed by BF3<middle dot>OEt2
    Yu, Shi-Wei
    Chen, Zu-Jia
    Li, Huan-Qing
    Li, Wen-Xi
    Li, Yun
    Li, Zong
    Wang, Zhao-Yang
    MOLECULES, 2024, 29 (15):
  • [26] Cp2TiCl2-Catalyzed Carboxylation of Aryl Chlorides with Carbon Dioxide in the Presence of n-BuMgCl
    Hang, Wei
    Yi, Yaping
    Xi, Chanjuan
    ORGANOMETALLICS, 2020, 39 (09) : 1476 - 1479
  • [27] Cp2TiCl2-catalyzed pinacol-type coupling of aliphatic aldehydes by use of zinc and chlorosilane
    Hirao, T
    Hatano, B
    Asahara, M
    Muguruma, Y
    Ogawa, A
    TETRAHEDRON LETTERS, 1998, 39 (29) : 5247 - 5248
  • [28] Cp2TiCl2-catalyzed synthesis of tetraalkyl-substituted pyrazines by the reaction of nitriles with EtAlCl2 and Mg
    Shaibakova, Mariya G.
    Rikhter, Nikita A.
    Dil'mukhametova, Leisan K.
    Ramazanov, Ilfir R.
    MENDELEEV COMMUNICATIONS, 2023, 33 (02) : 246 - 248
  • [29] A Dual Photoredox- and Cp2TiCl2-Catalyzed Approach for the Direct Access to α-Vinyl-β-hydroxy Esters
    Pinosa, Emanuele
    Gualandi, Andrea
    Fermi, Andrea
    Ceroni, Paola
    Cozzi, Pier Giorgio
    Calogero, Francesco
    EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 26 (38)
  • [30] Role of excess Zn in Cp2TiCl2-catalyzed styrene polymerizations from oxiranes, carbonyls and thermal initiators
    Asandei, Alexandru D.
    Chen, Yanhui
    Saha, Gobinda
    Moran, Isaac W.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
12345