Cp2TiCl2-Catalyzed cycloboration of monoterpene methylene derivatives with BF3 <middle dot> THF

被引：1
|
作者：
Tulyabaeva, L. I. [1 ]
Salakhutdinov, R. R. [1 ]
Tyumkina, T. V. [1 ]
Tulyabaev, A. R. [1 ]
机构：
[1] Russian Acad Sci, Inst Petrochem & Catalysis, 141 Prosp Oktyabrya, Ufa 450075, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2023年 / 72卷 / 10期
关键词：
monoterpenes; (-)-beta-pinene; (-)-camphene; L(-)-menthol; cycloboration; spiroboracarbocycles; BF3 center dot THF; Cp2TiCl2; ALPHA-OLEFINS; HYDROBORATION;
D O I：
10.1007/s11172-023-4046-0
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
1-Fluorine-substituted spiroboracarbocycles were first synthesized by cycloboration of monoterpenes ((-)-beta-pinene, (-)-camphene, and L(-)-menthol methylene derivative) with boron trifl uoride (BF3 center dot THF) in the presence of two-component catalytic system Cp2TiCl2/Mg in tetrahydrofuran.
引用
收藏
页码：2446 / 2452
页数：7
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