Aza-Dipyrrinate Stabilized Compounds with a Low-Valent Main Group Element

被引：1

作者：

Joshi, Prakash Chandra ^{[1
]}

Singh, Vivek Kumar ^{[1
]}

Shukla, Pratima ^{[1
]}

Kumar, Hemant ^{[1
]}

Shukla, Jyoti ^{[1
]}

Mahawar, Pritam ^{[1
]}

Singh, Dharmendra ^{[1
]}

Nagendran, Selvarajan ^{[1
]}

机构：

[1] Indian Inst Technol Delhi IIT Delhi, New Delhi 110016, India

来源：

CHEMISTRY-AN ASIAN JOURNAL | 2023年 / 18卷 / 17期

关键词：

a-DPM; germylenes; main group compounds; low-valent chemistry; group; 14; compounds; CHEMISTRY;

D O I：

10.1002/asia.202300365

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The possibility of using aza-dipyrromethene (a-DPM) ligands to stabilize compounds containing low-valent main group elements is demonstrated through the isolation of germylenes, a-DPM(p-tol)GeCl (2), a-DPM(Naph)GeCl (6), and a-DPM(Naph)GeN(TMS)(2) (7) (tol=tolyl, Naph=naphthyl). Because of the presence of the a-DPM ligand, these germylenes exhibit an absorption maximum at around 640 nm, a highly red-shifted value previously unknown for germylenes.

引用

页数：7

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