Kinetics and Mechanism of the Oxidation of CO to CO2 in the PdBr2-CuBr2-THF-H2O Catalytic System

被引：0
|
作者：
Putin, A. Yu. [1 ]
Katsman, E. A. [1 ]
Bruk, L. G. [1 ]
机构：
[1] MIREA Russian Technol Univ, Lomonosov Inst Fine Chem Technol, Moscow 119571, Russia
来源：
KINETICS AND CATALYSIS | 2023年 / 64卷 / 04期
关键词：
coupled process; oxidation of CO to CO2; kinetic model; palladium hydride complex; palladium(II) bromide complexes; copper bromide complexes; cyclohexene hydrocarboxylation; LOW-TEMPERATURE OXIDATION; CARBON-MONOXIDE; REDUCTION; OXYGEN; PALLADIUM(II); COMPLEXES; PD(II);
D O I：
10.1134/S0023158423040122
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the oxidation of CO to CO2 in the PdBr2-CuBr2-THF-H2O system outside the coupled process of cyclohexene hydrocarboxylation was studied. A kinetic model was constructed, and a reaction mechanism was proposed. It was found that the alkene hydrocarboxylation affects the oxidation of CO to CO2 in the coupled process, which was investigated previously.
引用
收藏
页码：412 / 420
页数：9
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