Kinetics and Mechanism of the Oxidation of CO to CO2 in the PdBr2-CuBr2-THF-H2O Catalytic System

被引：0
|
作者：
Putin, A. Yu. [1 ]
Katsman, E. A. [1 ]
Bruk, L. G. [1 ]
机构：
[1] MIREA Russian Technol Univ, Lomonosov Inst Fine Chem Technol, Moscow 119571, Russia
来源：
KINETICS AND CATALYSIS | 2023年 / 64卷 / 04期
关键词：
coupled process; oxidation of CO to CO2; kinetic model; palladium hydride complex; palladium(II) bromide complexes; copper bromide complexes; cyclohexene hydrocarboxylation; LOW-TEMPERATURE OXIDATION; CARBON-MONOXIDE; REDUCTION; OXYGEN; PALLADIUM(II); COMPLEXES; PD(II);
D O I：
10.1134/S0023158423040122
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The kinetics of the oxidation of CO to CO2 in the PdBr2-CuBr2-THF-H2O system outside the coupled process of cyclohexene hydrocarboxylation was studied. A kinetic model was constructed, and a reaction mechanism was proposed. It was found that the alkene hydrocarboxylation affects the oxidation of CO to CO2 in the coupled process, which was investigated previously.
引用
收藏
页码：412 / 420
页数：9
相关论文
共 50 条
  • [1] Kinetics and Mechanism of the Oxidation of CO to CO2 in the PdBr2–CuBr2–THF–H2O Catalytic System
    A. Yu. Putin
    E. A. Katsman
    L. G. Bruk
    Kinetics and Catalysis, 2023, 64 : 412 - 420
  • [2] The state of palladium and copper bromides in the PdBr2-CuBr2-THF-H2O system used in the conjugated process of cyclohexanecarboxylic acid production
    A. Yu. Putin
    E. Yu. Bukina
    E. A. Katsman
    K. V. Trunilina
    I. V. Oshanina
    L. G. Bruk
    O. N. Temkin
    Russian Journal of Physical Chemistry A, 2013, 87 : 465 - 472
  • [3] The state of palladium and copper bromides in the PdBr2-CuBr2-THF-H2O system used in the conjugated process of cyclohexanecarboxylic acid production
    Putin, A. Yu.
    Bukina, E. Yu.
    Katsman, E. A.
    Trunilina, K. V.
    Oshanina, I. V.
    Bruk, L. G.
    Temkin, O. N.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 87 (03) : 465 - 472
  • [4] Desorption kinetics of CO in char oxidation and gasification in O2, CO2 and H2O
    Karlstrom, Oskar
    Brink, Anders
    Hupa, Mikko
    COMBUSTION AND FLAME, 2015, 162 (03) : 788 - 796
  • [5] Kinetics of CO and H2 oxidation over CuO-CeO2 catalyst in H2 mixtures with CO2 and H2O
    Lee, Hyun Chan
    Kim, Dong Hyun
    CATALYSIS TODAY, 2008, 132 (1-4) : 109 - 116
  • [6] CHEMICAL KINETICS - REACTIONS H + CO2 = OH + CO AND CO2 + M = O + CO + M
    不详
    PYRODYNAMIC, 1968, 6 (01): : 101 - &
  • [7] OXIDATION OF ZINC VAPOR IN MIXTURES OF CO/CO2/A AND H2/H2O/A
    CLARKE, JA
    FRAY, DJ
    JOM-JOURNAL OF METALS, 1976, 28 (12): : A33 - A33
  • [8] Mechanism of Zn Particle Oxidation by H2O and CO2 in the Presence of ZnO
    Weibel, David
    Jovanovic, Zoran R.
    Galvez, Elena
    Steinfeld, Aldo
    CHEMISTRY OF MATERIALS, 2014, 26 (22) : 6486 - 6495
  • [9] CaS oxidation by reaction with CO2 and H2O
    Anthony, EJ
    Jia, L
    Qiu, K
    ENERGY & FUELS, 2003, 17 (02) : 363 - 368
  • [10] The Henry Coefficient of CO2 in the MEA-CO2-H2O System
    Li, Lichun
    Maeder, Marcel
    Burns, Robert
    Puxty, Graeme
    Clifford, Sarah
    Yu, Hai
    13TH INTERNATIONAL CONFERENCE ON GREENHOUSE GAS CONTROL TECHNOLOGIES, GHGT-13, 2017, 114 : 1841 - 1847
12345