Composition-independent Curie point (Tc) in ferroelectric (1-x)PbTiO3-xBi(Li1/2Nb1/2)O3 solid solution

被引：0
|
作者：
Kumar, Niraj [1 ]
Kumari, Ekta [1 ]
Krishna, P. Siva Ram [2 ]
Kalyani, Ajay Kumar [1 ]
机构：
[1] Indian Inst Technol Patna, Dept Met & Mat Engn, Patna 801106, Bihar, India
[2] Bhabha Atom Res Ctr, Solid State Phys Div, Mumbai, Maharashtra, India
来源：
JOURNAL OF THE AMERICAN CERAMIC SOCIETY | 2023年 / 106卷 / 01期
关键词：
ferroelectricity; ferroelectric materials; piezoelectric materials; properties; polycrystalline materials; MORPHOTROPIC PHASE-BOUNDARY; SYSTEM;
D O I：
10.1111/jace.18748
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
A new ferroelectric solid solution (1 - x)PbTiO3-xBi(Li1/2Nb1/2)O-3 has been explored to develop high-temperature piezoelectric material. An interesting observation has been found regarding its Curie point (T-C) and tetragonal lattice strain (c/a - 1). With increasing composition (x), the Curie point (T-C) decreases up to x = 0.10 and thereafter remains constant. In concurrence with the T-C, the tetragonal lattice strain (c/a - 1) follows a similar trend. Neutron powder diffraction analysis suggests this anomalous behavior is due to the robust off-centering characteristic of the Bi+3 ion 6S(2) lone pair effect at the A-site compared to ions at B-site.
引用
收藏
页码：430 / 437
页数：8
相关论文
共 50 条
  • [21] Morphotropic Phase Diagram and Dielectric and Ferroelectric Properties of (1-x)Ba(Sc1/2Nb1/2)O3-xPbTiO3 Solid Solution
    Wei, Qian
    Wang, Zujian
    Li, Xiuzhi
    Long, Xifa
    Ye, Zuo-Guang
    CHEMISTRY OF MATERIALS, 2009, 21 (03) : 506 - 510
  • [22] Characteristic electrical properties of Pb(Sc1/2Nb1/2)O3–PbTiO3 ferroelectric crystals
    Zujian Wang
    Xiuzhi Li
    Chao He
    Ying Liu
    Shujuan Han
    Shilie Pan
    Xifa Long
    Journal of Materials Science, 2015, 50 : 3970 - 3975
  • [23] Dielectric and energy storage properties of the (1-x)BaTiO3-xBi(Li1/3Hf2/3)O3 (0.08 ≤ x ≤ 0.14) ceramics
    Wang, Li-Min
    Liu, Qing-Xiang
    Zhou, Di
    MATERIALS LETTERS, 2021, 283 (283)
  • [24] Dielectric Properties and microstructures of solid solutions of (1-x)Pb(Mg1/3Nb2/3)O3-xPb(In1/2Nb1/2)O3
    Lee, KH
    Kim, H
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1998, 37 (9B): : 5265 - 5268
  • [25] Phase transition behaviors of (1-x)Pb(Yb1/2Nb1/2) O3-xBa(Yb1/2Nb1/2)O3 ceramics
    Kim, HS
    Kim, JH
    Choo, WK
    Setter, N
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2001, 21 (10-11) : 1665 - 1668
  • [26] NEW CD(FE1/2NB1/2)O3 FERROELECTRIC
    VENEVTSEV, YN
    IVANOVA, VV
    GOLOVNIN, VA
    KASHLINSKII, AI
    KOZLOVA, LA
    KUZMIN, RN
    IZVESTIYA AKADEMII NAUK SSSR SERIYA FIZICHESKAYA, 1971, 35 (09): : 1829 - +
  • [27] Structural evolution of a high Tc ferroelectric (x)Bi(Zn1/2Ti1/2)O3-(1-x)PbTiO3 solid solution
    Zhang, X. D.
    Kwon, Daeyoung
    Kim, Bog G.
    APPLIED PHYSICS LETTERS, 2008, 92 (08)
  • [28] Ferroelectricity of solid solution Pb[(Yb1/2Nb1/2)1/3Zr 2/3]O3
    Yokosuka, Masaru, 1600, JJAP, Minato-ku, Japan (33):
  • [29] Study on xPb(Y1/2Nb1/2)O3- (1-x)Pb(Zr1/2Ti1/2)O3 ferroelectric ceramics
    Dong, H.M.
    Wang, J.F.
    Wang, Y.J.
    Chen, H.C.
    Tian, Q.
    Yadian Yu Shengguang/Piezoelectrics and Acoustooptics, 2001, 23 (05):
  • [30] Phase transition studies in multiferroic Pb(Fe1/2Nb1/2)O3 and its solid solution with PbTiO3
    Singh, Satendra Pal
    Pandey, Dhananjai
    Yusuf, S. M.
    Yoon, Songhak
    Shin, Namsoo
    Baik, Sunggi
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : C524 - C525
12345