Synthesis, structure and property investigation of a three-dimensional Zn(II) metal-organic frameworks

被引：0
|
作者：
Jiang, Cong-Cong [1 ]
Xu, Dong-Xin [1 ]
Bai, Pei-Xin [1 ]
Wang, Yong-Xiang [1 ]
Zhang, Cheng [2 ]
Wang, Jun [1 ]
Sun, Shi-Xin [1 ]
机构：
[1] Yancheng Teachers Univ, Coll Chem & Environm Engn, Yancheng 224002, Peoples R China
[2] Suzhou Univ Sci & Technol, Sch Phys Sci & Technol, Jiangsu Key Lab Micro & Nano Heat Fluid Flow Techn, Suzhou 215009, Peoples R China
来源：
FUNCTIONAL MATERIALS LETTERS | 2023年 / 16卷 / 06期
基金：
中国国家自然科学基金;
关键词：
Metal organic frameworks; 5-tert-butyl isophthalic acid; photoluminescence properties; photocatalytic properties;
D O I：
10.1142/S1793604723500200
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A new three-dimensional Zn(II) complex named [Zn(1,3-BMIB)(TBIP)& sdot;2H2O]n (1) (containning 1,3-BMIB = 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene, H2TBIP=5-tert-butyl isophthalic acid) had been prepared by hydrothermal synthesis. Systematic structural characterization, especially the single crystal X-ray diffraction method, discreetly reveal the complex 1 exhibits three-dimensional (3D) framework with CdSO4 topology. The 3D crystrals 1 display solid-state fluorescence behavior at room temperature, indicating the potential of the candidate materials for absorbing and using visible light. The photocatalytic properties of compound 1 were estimated through the model photodecomposition dye pollutants using methylene blue (MB) and rhodamine B (RhB) under visible light irradiation.
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页数：4
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